DI-N-BUTYLGERMANE

Base Information

• Chemical Name: DI-N-BUTYLGERMANE
• CAS No.: 29823-30-1
• Molecular Formula: C₈H₂₀Ge
• Molecular Weight: 188.837
• Mol file: 29823-30-1.mol

Synonyms:

Chemical Property of DI-N-BUTYLGERMANE

Chemical Property:

• Refractive Index: 1.4428
• Boiling Point: 70-5°C 15mm
• Density: 0,978 g/cm3

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of DI-N-BUTYLGERMANE

There total 7 articles about DI-N-BUTYLGERMANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 5.9%

allyldibutylgermane (87513-91-5) → diallyldibutylgermane (87513-87-9) + dibutylgermane (29823-30-1)

Guidance literature:

With dibenzoyl peroxide; In benzene; hydrogermane (0.51 mmol), dibenzoyl peroxide (0.02 mmol) and benzene (50.64 mmol) heated at 80°C for 15 h; isolated by preparative GLC;

DOI:10.1246/bcsj.56.1875

Reference yield: 4.9%

dibutyl(2-methylallyl)germane (87513-86-8) → dibutylbis(2-methylallyl)germane (87513-88-0) + dibutylgermane (29823-30-1)

Guidance literature:

With dibenzoyl peroxide; In benzene; hydrogermane (0.77 mmol), dibenzoyl peroxide (0.07 mmol) and benzene (77.71 mmol) heated at 80°C for 15 h; isolated by preparative GLC;

DOI:10.1246/bcsj.56.1875

Reference yield:

→ dibutylgermane (29823-30-1)

Guidance literature:

With lithium aluminium tetrahydride; diethyl ether;

upstream raw materials:

allyldibutylgermane

dibutyl(2-methylallyl)germane

lithium aluminium tetrahydride

dibutyldichlorogermane

Downstream raw materials:

(C₂H₅)3SiOGe(C₄H₉)2OSi(C₂H₅)3

trimeres Di-n-butyl-germaniumoxid

Refernces

• 1、 Mochida, Kunio,Miyagawa, Isoo. "The Thermal Reactions of Allyl-substituted Germyl Radicals". . p. 1875 - 1876. Retrieved 2007/10/02.