cyclopentadienyl(1,2-bis(diphenylphosphino)ethane)FeC(CN)3

Base Information

• Chemical Name: cyclopentadienyl(1,2-bis(diphenylphosphino)ethane)FeC(CN)3
• CAS No.: 497844-58-3
• Molecular Formula: C₃₅H₂₉FeN₃P₂
• Molecular Weight: 609.43
• Mol file: 497844-58-3.mol

Synonyms:

Chemical Property of cyclopentadienyl(1,2-bis(diphenylphosphino)ethane)FeC(CN)3

Chemical Property:

Purity/Quality:

Safty Information:

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Useful:

Technology Process of cyclopentadienyl(1,2-bis(diphenylphosphino)ethane)FeC(CN)3

There total 1 articles about cyclopentadienyl(1,2-bis(diphenylphosphino)ethane)FeC(CN)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

[CpFeCl(dppe)] (32843-51-9) + potassium tricyanomethanide (34171-69-2) → cyclopentadienyl(1,2-bis(diphenylphosphino)ethane)FeC(CN)3 (497844-58-3)

Guidance literature:

In methanol; dichloromethane; under Ar; soln. of KC(CN)3 in MeOH added to soln. of Cp(dppe)FeCl in CH2Cl2, stirred at room temp. for 2 h; solvent removed, residue dissolved in CH2Cl2, column chromy. (alumina, CH2Cl2-MeOH (50:1)); elem. anal.;

DOI:10.1021/ic025879t

Reference yield: 85.0%

[CpFeCl(dppe)] (32843-51-9) + cyclopentadienyl(1,2-bis(diphenylphosphino)ethane)FeC(CN)3 (497844-58-3) + potassium trifluoromethansulfonate (2926-27-4) → [(cyclopentadienyl(1,2-bis(diphenylphosphino)ethane)Fe)2C(CN)3](CF3SO3)

Guidance literature:

In dichloromethane; under Ar; soln. of Cp(dppe)FeCl in CH2Cl2 added to soln. of Cp(dppe)FeC(CN)3 in CH2Cl2, soln. of CF3SO3K in MeOH added, stirred at room temp. for 4 h; evapd. in vacuo, residue dissolved in CH2Cl2, filtered, filtrate layeredwith petroleum ether; elem. anal.;

DOI:10.1021/ic025879t

upstream raw materials:

[CpFeCl(dppe)]

potassium tricyanomethanide