1,1'-bis(β,β-diethoxyethyl)cobaltocenium tetraphenylborate

Base Information

Chemical Name:1,1'-bis(β,β-diethoxyethyl)cobaltocenium tetraphenylborate
CAS No.:177339-45-6
Molecular Formula:C₂₂H₃₄CoO₄*C₂₄H₂₀B
Molecular Weight:740.737
Hs Code.:

Synonyms:

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Chemical Property of 1,1'-bis(β,β-diethoxyethyl)cobaltocenium tetraphenylborate

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Technology Process of 1,1'-bis(β,β-diethoxyethyl)cobaltocenium tetraphenylborate

There total 1 articles about 1,1'-bis(β,β-diethoxyethyl)cobaltocenium tetraphenylborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 143-66-8
sodium tetraphenyl borate

: 177339-61-6
(β,β-diethoxyethyl)cyclopentadiene

: cobalt(II) bromide

: 177339-45-6
1,1'-bis(β,β-diethoxyethyl)cobaltocenium tetraphenylborate

Guidance literature:: With NaH; In tetrahydrofuran; methanol; N,N-dimethyl-formamide; byproducts: H2; N2-atmosphere; mixing equimolar amts. of cyclopentadiene derivative and NaH (in THF), stirring (room temp., 1 h), cooling in ice-bath, addn. of 0.5 equiv. CoBr2 (in DMF), stirring (room temp., overnight), filtration,pptn. on addn. NaBPh4 (in MeOH); filtration, recrystn. (MeOH); elem. anal.;
DOI:10.1016/0022-328X(95)05911-8

Reference yield: 79.0%

: 177339-45-6
1,1'-bis(β,β-diethoxyethyl)cobaltocenium tetraphenylborate

: 104-15-4
toluene-4-sulfonic acid

: 177339-53-6
2,4-(1,1'-di[η(5)-cyclopentadienyl]cobalt(III))-but-2-ene-1-al tosylate

Guidance literature:: With H₂O; In toluene; refluxing Co-complex with H2O and excess of p-toluenesulfonic acid for 2h (pptn.); filtration, washing (PhMe), drying; can be recrystallized (MeCN); elem. anal.;
DOI:10.1016/0022-328X(95)05911-8

Reference yield:

: 177339-45-6
1,1'-bis(β,β-diethoxyethyl)cobaltocenium tetraphenylborate

: 143-66-8
sodium tetraphenyl borate

: 177339-55-8
2,4-(1,1'-di[η(5)-cyclopentadienyl]cobalt(III))-but-2-ene-1-al tetraphenylborate

Guidance literature:: With HCl; In methanol; water; refluxing Co-complex with HCl and NaBPh4 (pptn.); collection;
DOI:10.1016/0022-328X(95)05911-8