Ir2(μ-N(p-tolyl))(CO)2(bis(diphenylphosphino)methane)2

Base Information

• Chemical Name: Ir2(μ-N(p-tolyl))(CO)2(bis(diphenylphosphino)methane)2
• CAS No.: 159696-08-9
• Molecular Formula: C₅₉H₅₁Ir₂NO₂P₄
• Molecular Weight: 1314.39
• Mol file: 159696-08-9.mol

Synonyms:

Chemical Property of Ir2(μ-N(p-tolyl))(CO)2(bis(diphenylphosphino)methane)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of Ir2(μ-N(p-tolyl))(CO)2(bis(diphenylphosphino)methane)2

There total 1 articles about Ir2(μ-N(p-tolyl))(CO)2(bis(diphenylphosphino)methane)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

Ir2Cl2(CO)2(bis(diphenylphosphino)methane)2 (66125-35-7,90553-00-7,97487-54-2,99511-21-4) + lithium p-toluidinate (50636-21-0) → Ir2(μ-N(p-tolyl))(CO)2(bis(diphenylphosphino)methane)2 (159696-08-9)

Guidance literature:

In tetrahydrofuran; byproducts: LiCl; N2-atmosphere; addn. of excess of amine to Ir-complex, stirring for 1.5h; evapn. (vac.), dissoln. in PhMe, filtration off of LiCl, concn. (vac.),pptn. on hexane addn., repptn. (CH2Cl2/hexane), filtration, washing (hexane), drying (vac.);

Reference yield:

Ir2(μ-N(p-tolyl))(CO)2(bis(diphenylphosphino)methane)2 (159696-08-9) → (Ir2(CO)2(μ-CO)(dppm)2) (97487-41-7)

Guidance literature:

With CO; In not given; byproducts: p-MeC6H4NH2; N2-atmosphere; 1 equiv. CO; not isolated, detd. by (31)P-NMR and IR spectroscopy;

Reference yield:

Ir2(μ-N(p-tolyl))(CO)2(bis(diphenylphosphino)methane)2 (159696-08-9) → Ir2(CO)4(μ-bis(diphenylphosphino)methane)2

Guidance literature:

With CO; In dichloromethane; N2-atmosphere; 5 equivs. CO; not isolated, detd. by (31)P-NMR and IR spectroscopy;

upstream raw materials:

Ir₂Cl₂(CO)2(bis(diphenylphosphino)methane)2

lithium p-toluidinate

Downstream raw materials:

(Ir2(CO)2(μ-CO)(dppm)2)