(phenyl)methyl(η5-indenyl)(trimethylphosphine)iridium

Base Information

Chemical Name:(phenyl)methyl(η5-indenyl)(trimethylphosphine)iridium
CAS No.:139377-90-5
Molecular Formula:C₁₉H₂₄IrP
Molecular Weight:475.593
Hs Code.:

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Chemical Property of (phenyl)methyl(η5-indenyl)(trimethylphosphine)iridium

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Technology Process of (phenyl)methyl(η5-indenyl)(trimethylphosphine)iridium

There total 1 articles about (phenyl)methyl(η5-indenyl)(trimethylphosphine)iridium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 26.0%

: iodo(phenyl)(η5-indenyl)(trimethylphosphine)iridium*0.33toluene

: 139377-90-5
(phenyl)methyl(η5-indenyl)(trimethylphosphine)iridium

Guidance literature:: With CH₃MgBr; In diethyl ether; toluene; addn. of 2.25 equiv of CH3MgBr in Et2O by syringe to a stirred soln. of the iodo(phenyl) complex in toluene under dry N2 or Ar, stirring (1 d), color change from orange to light yellow; passing the mixt. through a small pad of alumina III, elution (Et2O, 3 times), removal of volatiles (vac.), dissolving the residue in a minimum amt. of toluene, column chromy. (alumina III, pentane/Et2O (3:1)), removal of solvent; elem. anal.;

Reference yield:

: 139377-90-5
(phenyl)methyl(η5-indenyl)(trimethylphosphine)iridium

: 139655-76-8
(C₉H₇)(P(CH₃)3)(CO)2Ir(C₆H₅)(CH₃)

Guidance literature:: With carbon monoxide; In diethyl ether; degassing the phenylmethyl complex in Et2O under dry N2 or Ar (two freeze-pump-thaw cycles), pressurizing with 700 Torr of CO (ambient temp.); removal of volatiles (vac.); 3:2 mixt. of two diastereomeric dicarbonyl adducts;;
DOI:10.1021/om00041a014