thulium tetraphenylphorphyrin chloride dimethoxyethane complex

Base Information

• Chemical Name: thulium tetraphenylphorphyrin chloride dimethoxyethane complex
• CAS No.: 421548-43-8
• Molecular Formula: C₄₈H₃₈ClN₄O₂Tm
• Molecular Weight: 907.243

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Chemical Property of thulium tetraphenylphorphyrin chloride dimethoxyethane complex

Chemical Property:

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Technology Process of thulium tetraphenylphorphyrin chloride dimethoxyethane complex

There total 1 articles about thulium tetraphenylphorphyrin chloride dimethoxyethane complex which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

thulium trichloride tris(tetrahydrofuran) + dilithiotetraphenylporphyrin bisdimethoxyethane → thulium tetraphenylphorphyrin chloride dimethoxyethane complex (421548-43-8)

Guidance literature:

In toluene; byproducts: LiCl; toluene, reflux, 4 h; hot filtered, reduced in vol., cooled to 0°C;

DOI:10.1021/ic015612e

Reference yield: 81.0%

thulium tetraphenylphorphyrin chloride dimethoxyethane complex (421548-43-8) + potassium tris(1-pyrazolyl)borate → Tm(5,10,15,20-tetraphenylporphyrinate)(hydridotris(1-pyrazolyl)borate)

Guidance literature:

In 1,2-dimethoxyethane; under N2; borate added to soln. of Tm complex in DME under vigorous stirring, stirred at room temp. for 12 h; solvent removed in vacuo, residue extd. with CH2Cl2, extract filtered, filtrate layered with pentane, crystd. overnight, crystals sepd., furthercrop of crystals from mother liquor after filtration, concn. and coolin g to -78°C; elem. anal.;

DOI:10.1021/ic034217g

Reference yield: 64.0%

sodium (cyclopentadienyl)tris(diethylphosphinito)cobaltate(I) + thulium tetraphenylphorphyrin chloride dimethoxyethane complex (421548-43-8) → Tm(5,10,15,20-tetraphenylporphyrinate)((cyclopentadienyl)tris(diethylphosphinito)cobaltate(I))

Guidance literature:

In 1,2-dimethoxyethane; under N2; solid Na(CpCo(PO(OEt)2)3) added to soln. of Tm complex in DME,stirred at room temp. for 12 h; solvent removed in vacuo, residue extd. with toluene, filtered, concd., layered with pentane, cooled to -78°C for 5 h; elem. anal.;

DOI:10.1021/ic034217g

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