(4S,5S,6S,10S,11S,12R,14R)-11-(benzyloxy)-14-(6-ethyl-3,5-dimethyl-4-oxo-4H-pyran-2-yl)-4,6,8,10,12-pentamethyl-5-hydroxy-pentadecane-3,7,9,13-tetraone

Base Information

Chemical Name:(4S,5S,6S,10S,11S,12R,14R)-11-(benzyloxy)-14-(6-ethyl-3,5-dimethyl-4-oxo-4H-pyran-2-yl)-4,6,8,10,12-pentamethyl-5-hydroxy-pentadecane-3,7,9,13-tetraone
CAS No.:1228104-47-9
Molecular Formula:C₃₆H₅₀O₈
Molecular Weight:610.788
Hs Code.:

(4S,5S,6S,10S,11S,12R,14R)-11-(benzyloxy)-14-(6-ethyl-3,5-dimethyl-4-oxo-4H-pyran-2-yl)-4,6,8,10,12-pentamethyl-5-hydroxy-pentadecane-3,7,9,13-tetraone

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Chemical Property of (4S,5S,6S,10S,11S,12R,14R)-11-(benzyloxy)-14-(6-ethyl-3,5-dimethyl-4-oxo-4H-pyran-2-yl)-4,6,8,10,12-pentamethyl-5-hydroxy-pentadecane-3,7,9,13-tetraone

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Technology Process of (4S,5S,6S,10S,11S,12R,14R)-11-(benzyloxy)-14-(6-ethyl-3,5-dimethyl-4-oxo-4H-pyran-2-yl)-4,6,8,10,12-pentamethyl-5-hydroxy-pentadecane-3,7,9,13-tetraone

There total 1 articles about (4S,5S,6S,10S,11S,12R,14R)-11-(benzyloxy)-14-(6-ethyl-3,5-dimethyl-4-oxo-4H-pyran-2-yl)-4,6,8,10,12-pentamethyl-5-hydroxy-pentadecane-3,7,9,13-tetraone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1228104-16-2
(4S,5S,6S,10S,11S,12R,14R)-11-(benzyloxy)-14-(6-ethyl-3,5-dimethyl-4-oxo-4H-pyran-2-yl)-4,6,8,10,12-pentamethyl-5-((triethylsilyl)oxy)pentadecane-3,7,9,13-tetraone

: 1228104-47-9
(4S,5S,6S,10S,11S,12R,14R)-11-(benzyloxy)-14-(6-ethyl-3,5-dimethyl-4-oxo-4H-pyran-2-yl)-4,6,8,10,12-pentamethyl-5-hydroxy-pentadecane-3,7,9,13-tetraone

Guidance literature:: With pyridine; pyridine hydrogenfluoride; In tetrahydrofuran; water; at 20 ℃; for 4h;
DOI:10.1021/ja102356j

Reference yield: 70.0%

: 1228104-47-9
(4S,5S,6S,10S,11S,12R,14R)-11-(benzyloxy)-14-(6-ethyl-3,5-dimethyl-4-oxo-4H-pyran-2-yl)-4,6,8,10,12-pentamethyl-5-hydroxy-pentadecane-3,7,9,13-tetraone

: 123003-45-2
baconipyrone A

: baconipyrone C

Guidance literature:: (4S,5S,6S,10S,11S,12R,14R)-11-(benzyloxy)-14-(6-ethyl-3,5-dimethyl-4-oxo-4H-pyran-2-yl)-4,6,8,10,12-pentamethyl-5-hydroxy-pentadecane-3,7,9,13-tetraone; With aluminum oxide; In ethanol; for 7h; Reflux;

With 5% Pd(II)/C(eggshell); hydrogen; In ethanol; for 24h;
DOI:10.1021/ja102356j