Pd(CH₃C₆H₃N₂C₆H₄CH₃)(((C₆H₅)2P)2CH₂)⁽¹⁺⁾*OSO₂CF₃^(1-)=[Pd(CH₃C₆H₃N₂C₆H₄CH₃)(((C₆H₅)2P)2CH₂)]SO₃CF₃

Base Information

• Chemical Name: Pd(CH₃C₆H₃N₂C₆H₄CH₃)(((C₆H₅)2P)2CH₂)⁽¹⁺⁾*OSO₂CF₃^(1-)=[Pd(CH₃C₆H₃N₂C₆H₄CH₃)(((C₆H₅)2P)2CH₂)]SO₃CF₃
• CAS No.: 189198-08-1
• Molecular Formula: CF₃O₃S*C₃₉H₃₅N₂P₂Pd
• Molecular Weight: 849.158
• Mol file: 189198-08-1.mol

Synonyms:

Chemical Property of Pd(CH₃C₆H₃N₂C₆H₄CH₃)(((C₆H₅)2P)2CH₂)⁽¹⁺⁾*OSO₂CF₃^(1-)=[Pd(CH₃C₆H₃N₂C₆H₄CH₃)(((C₆H₅)2P)2CH₂)]SO₃CF₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Pd(CH₃C₆H₃N₂C₆H₄CH₃)(((C₆H₅)2P)2CH₂)⁽¹⁺⁾*OSO₂CF₃^(1-)=[Pd(CH₃C₆H₃N₂C₆H₄CH₃)(((C₆H₅)2P)2CH₂)]SO₃CF₃

There total 1 articles about Pd(CH₃C₆H₃N₂C₆H₄CH₃)(((C₆H₅)2P)2CH₂)⁽¹⁺⁾*OSO₂CF₃^(1-)=[Pd(CH₃C₆H₃N₂C₆H₄CH₃)(((C₆H₅)2P)2CH₂)]SO₃CF₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

silver hexafluoroantimonate (26042-64-8) + bis(μ-chloro)bis(azotoluene-C2,N)dipalladium(II) + bis-diphenylphosphinomethane (2071-20-7) → [Pd(MeC6H3N2C6H4Me)(η(2)-bis(diphenylphosphino)methane)]OSO2CF3 (189198-08-1)

Guidance literature:

In acetone; byproducts: AgCl; moisture free atmosphere; stirring (room temp., 1 h); evapn., extg. (CH2Cl2), filtering, pptn. on concg. and Et2O addn.; elem.anal.;

DOI:10.1021/om961094h

Reference yield: 83.0%

sodium azide + Pd(CH3C6H3N2C6H4CH3)(((C6H5)2P)2CH2)(1+)*OSO2CF3(1-)=[Pd(CH3C6H3N2C6H4CH3)(((C6H5)2P)2CH2)]SO3CF3 (189198-08-1) → [Pd2(μ2-N3)(MeC6H3N2C6H4Me)2(μ2-bis(diphenylphosphino)methane)2]SO3CF3

Guidance literature:

In acetone; stirring (8 h); evapn., CH2Cl2 addn., concg., pptn. on Et2O and n-hexane addn.; elem. anal.;

DOI:10.1021/om980445k

Reference yield: 36.0%

[Pd(MeC6H3N2C6H4Me)(η(2)-bis(diphenylphosphino)methane)]OSO2CF3 (189198-08-1) + oxygen (80937-33-3) → [Pd(κ2-C,N'-C6H3(N=NC6H4-Me-4')-2-Me-5)(κ2-P,O-bis(diphenylphosphino)methane-O)]CF3SO3 (511519-96-3)

Guidance literature:

In toluene; soln. of Pd complex in toluene was refluxed for 8 h; concd.; Et2O added; pptd.; elem. anal.;

DOI:10.1016/S0022-328X(02)01729-1

upstream raw materials:

silver hexafluoroantimonate

bis-diphenylphosphinomethane

Downstream raw materials:

[Pd(κ2-C,N'-C6H3(N=NC6H4-Me-4')-2-Me-5)(κ2-P,O-bis(diphenylphosphino)methane-O)]CF3SO3

[Pd(κ1-C-C6H3(N=NC6H4-Me-4')-2-Me-5)(PPh3)(κ2-bis(diphenylphosphino)methane)]CF3SO3