bis[N-(3,5-dichlorosalicylidene)anilinato]dibenzyltin(IV)

Base Information

• Chemical Name: bis[N-(3,5-dichlorosalicylidene)anilinato]dibenzyltin(IV)
• CAS No.: 1122709-05-0
• Molecular Formula: C₄₀H₃₀Cl₄N₂O₂Sn
• Molecular Weight: 831.212
• Mol file: 1122709-05-0.mol

Synonyms:

Chemical Property of bis[N-(3,5-dichlorosalicylidene)anilinato]dibenzyltin(IV)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis[N-(3,5-dichlorosalicylidene)anilinato]dibenzyltin(IV)

There total 1 articles about bis[N-(3,5-dichlorosalicylidene)anilinato]dibenzyltin(IV) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.0%

dibenzyltin(IV) dichloride (3002-01-5) + N-(3,5-dichlorosalicylidene)aniline (161696-84-0) → bis[N-(3,5-dichlorosalicylidene)anilinato]dibenzyltin(IV) (1122709-05-0)

Guidance literature:

With NaH; In tetrahydrofuran; under N2, Schlenk or glove-box techniques; soln. of org. ligand (4.13 mmol) added to NaH soln. (2.06 mmol) (0°C); warmed to room temp.; stirred; added to soln. of Cl2Sn(CH2Ph)2 (2.06 mmol) (0°C); warmedto room temp.; stirred overnight; solvent removed (vac.); extd. with toluene; concd.; stored (-20°C) overnight; elem. anal.;

DOI:10.1002/ejic.200700937

Reference yield:

bis[N-(3,5-dichlorosalicylidene)anilinato]dibenzyltin(IV) (1122709-05-0) + tris(pentafluorophenyl)borate (1109-15-5) → (bis[N-(3,5-dichlorosalicylidene)anilinato]benzyltin(IV))(1+) (1122709-09-4)

Guidance literature:

In dichloromethane-d2; under N2 using Schlenk or glove-box techniques; Sn complex (18 μmol) dissolved in dry CD2Cl2; B(C6F5)3 (18 μmol) added; not isolated; analyzed by NMR;

DOI:10.1002/ejic.200700937

upstream raw materials:

dibenzyltin(IV) dichloride

N-(3,5-dichlorosalicylidene)aniline

Downstream raw materials:

(bis[N-(3,5-dichlorosalicylidene)anilinato]benzyltin(IV))⁽¹⁺⁾