cyclohexanethiolato-thallium(I)

Base Information

• Chemical Name: cyclohexanethiolato-thallium(I)
• CAS No.: 145703-75-9
• Molecular Formula: C₆H₁₁S*Tl
• Molecular Weight: 319.602
• Mol file: 145703-75-9.mol

Synonyms:

Chemical Property of cyclohexanethiolato-thallium(I)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cyclohexanethiolato-thallium(I)

There total 1 articles about cyclohexanethiolato-thallium(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 32.0%

thallium(I) carbonate + sodium cyclohexanethiolate (50729-68-5) → cyclohexanethiolato-thallium(I) (145703-75-9)

Guidance literature:

In ethanol; byproducts: Na2CO3; N2 atmosphere; addn. of ethanolic soln. of NaSC6H11 to suspn. of Tl2CO3 in ethanol, refluxing for 1 h; filtration (hot), crystn. on slow cooling; elem anal.;

Reference yield: 51.0%

cyclohexanethiolato-thallium(I) (145703-75-9) + (2,4-bis(2,6-dimethylphenylimido)pentane-H)ZnCl2Li(tetrahydrofuran)3*n(tetrahydrofuran) + pentane (109-66-0,8031-35-4,9078-70-0) → ((2,4-bis(2,6-dimethylphenylimido)pentane-H)Zn(μ-cyclohexylthiolate)2Tl)2*2(pentane)

Guidance literature:

In tetrahydrofuran; under N2, glovebox or Schlenk techniques; suspn. of TlSCy (1.51 mmol) inTHF added to soln. of Zn complex (0.754 mmol) in THF under stirring; mi xt. stirred overnight; filtered through Celite; filtrate evapd. under vac.; solid dissolved in CH2Cl2; filtered through Celite; filtrate evapd. under vac.; solid washed with pentane; recrystd. from pentane; elem. anal.;

DOI:10.1016/j.ica.2006.07.049

Reference yield: 44.0%

cyclohexanethiolato-thallium(I) (145703-75-9) + (2,4-bis(2,6-dimethylphenylimido)pentane-H)ZnCl2Li(tetrahydrofuran)3*n(tetrahydrofuran) → ((2,4-bis(2,6-dimethylphenylimido)pentane-H)Zn(μ-cyclohexylthiolate))2 (923955-90-2)

Guidance literature:

In tetrahydrofuran; under N2, glovebox or Schlenk technique; suspn. of TlSCy (0.452 mmol) inTHF added to soln. of Zn complex (0.452 mmol) in THF under stirring; mi xt. stirred for 2 h; evapd. under vac.; solid taken up in CH2Cl2; filtered through Celite; filtrate concd.; stored at -35°C overnight; elem. anal.;

DOI:10.1016/j.ica.2006.07.049

upstream raw materials:

sodium cyclohexanethiolate

Downstream raw materials:

((2,4-bis(2,6-dimethylphenylimido)pentane-H)Zn(μ-cyclohexylthiolate))2

(iPr)2TpZn(SCy)