C₂₅H₂₅F₆NP⁽¹⁺⁾*C₁₂H₈O₄P^(1-)

Base Information

• Chemical Name: C₂₅H₂₅F₆NP⁽¹⁺⁾*C₁₂H₈O₄P^(1-)
• CAS No.: 1417444-05-3
• Molecular Formula: C₁₂H₈O₄P*C₂₅H₂₅F₆NP
• Molecular Weight: 731.611
• Mol file: 1417444-05-3.mol

Synonyms:

Chemical Property of C₂₅H₂₅F₆NP⁽¹⁺⁾*C₁₂H₈O₄P^(1-)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₂₅H₂₅F₆NP⁽¹⁺⁾*C₁₂H₈O₄P^(1-)

There total 4 articles about C₂₅H₂₅F₆NP⁽¹⁺⁾*C₁₂H₈O₄P^(1-) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,1'-biphenyl-2,2'-diyl hydrogen phosphate (35227-84-0,124756-11-2,124756-12-3) + C25H25F6NP(1+)*CF3O3S(1-) (1417444-08-6) → C25H25F6NP(1+)*C12H8O4P(1-) (1417444-05-3)

Guidance literature:

C₂₅H₂₅F₆NP⁽¹⁺⁾*CF₃O₃S^(1-); With Amberlyst A-26 (OH^－ form); In methanol;

1,1'-biphenyl-2,2'-diyl hydrogen phosphate; In methanol; at 20 ℃; for 0.5h;

DOI:10.1021/ja312125a

Reference yield:

(-)-(S)-N,N-dimethyl-1-phenylethylamine (17279-31-1) → C25H25F6NP(1+)*C12H8O4P(1-) (1417444-05-3)

Guidance literature:

Multi-step reaction with 4 steps

1.1: n-butyllithium / diethyl ether; hexane / 10 h / 20 °C

1.2: 0.5 h / -78 - 20 °C

2.1: n-butyllithium / diethyl ether; hexane / Inert atmosphere

2.2: 5 h / -78 - 20 °C / Inert atmosphere

3.1: acetonitrile / 1 h / 20 °C

4.1: Amberlyst A-26 (OH^－ form) / methanol

4.2: 0.5 h / 20 °C

With n-butyllithium; In methanol; diethyl ether; hexane; acetonitrile;

DOI:10.1021/ja312125a

Reference yield:

C10H14Cl2NP → C25H25F6NP(1+)*C12H8O4P(1-) (1417444-05-3)

Guidance literature:

Multi-step reaction with 3 steps

1.1: n-butyllithium / diethyl ether; hexane / Inert atmosphere

1.2: 5 h / -78 - 20 °C / Inert atmosphere

2.1: acetonitrile / 1 h / 20 °C

3.1: Amberlyst A-26 (OH^－ form) / methanol

3.2: 0.5 h / 20 °C

With n-butyllithium; In methanol; diethyl ether; hexane; acetonitrile;

DOI:10.1021/ja312125a

upstream raw materials:

(-)-(S)-N,N-dimethyl-1-phenylethylamine

C₂₄H₂₂F₆NP

1,1'-biphenyl-2,2'-diyl hydrogen phosphate

C₂₅H₂₅F₆NP⁽¹⁺⁾*CF₃O₃S^(1-)