Benzene, 1-(1-azidoethyl)-3-bromo-, (S)-

Base Information

Chemical Name:Benzene, 1-(1-azidoethyl)-3-bromo-, (S)-
CAS No.:139305-97-8
Molecular Formula:C8H8BrN3
Molecular Weight:226.076
Hs Code.:
DSSTox Substance ID:DTXSID501276774

Synonyms:Benzene, 1-(1-azidoethyl)-3-bromo-, (S)-;DTXSID501276774;AKOS026733033;139305-97-8

Suppliers and Price of Benzene, 1-(1-azidoethyl)-3-bromo-, (S)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Benzene, 1-(1-azidoethyl)-3-bromo-, (S)-

Chemical Property:

XLogP3:3.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:224.99016
Heavy Atom Count:12
Complexity:189

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C1=CC(=CC=C1)Br)N=[N+]=[N-]
Isomeric SMILES:C[C@@H](C1=CC(=CC=C1)Br)N=[N+]=[N-]

Technology Process of Benzene, 1-(1-azidoethyl)-3-bromo-, (S)-

There total 2 articles about Benzene, 1-(1-azidoethyl)-3-bromo-, (S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 52780-14-0,64382-14-5,134615-22-8,134615-24-0
(R)-1-(3-bromophenyl)ethanol

: 139305-97-8
1-((S)-1-Azido-ethyl)-3-bromo-benzene

Guidance literature:: With tris-(2-chloro-ethyl)-amine; triphenylphosphine; diethylazodicarboxylate; In toluene; for 2h; Ambient temperature;
DOI:10.1016/0040-4039(91)80469-M

Reference yield:

: 2142-63-4
1-(3-Bromophenyl)ethanone

: 139305-97-8
1-((S)-1-Azido-ethyl)-3-bromo-benzene

Guidance literature:: Multi-step reaction with 2 steps

1: 90 percent / BH₃ / R-oxazaborolidine 3a / tetrahydrofuran / Ambient temperature

2: 100 percent / PPh₃, HN₃, DEAD / toluene / 2 h / Ambient temperature

With tris-(2-chloro-ethyl)-amine; borane; triphenylphosphine; diethylazodicarboxylate; R-oxazaborolidine 3a; In tetrahydrofuran; toluene;
DOI:10.1016/0040-4039(91)80469-M

Reference yield:

: 139305-97-8
1-((S)-1-Azido-ethyl)-3-bromo-benzene

: 74877-08-0,139305-96-7
(S)-1-(3-bromophenyl)ethanamine

Guidance literature:: With hydrogenchloride; triphenylphosphine; In tetrahydrofuran; Yield given; Ambient temperature;
DOI:10.1016/0040-4039(91)80469-M