[(1aR,4S,4aS,7R,7aS,7bR)-1,1,7-trimethyldecahydro-4H-4,7-epoxycyclopropa[e]azulen-4-yl]methanol

Base Information

• Chemical Name: [(1aR,4S,4aS,7R,7aS,7bR)-1,1,7-trimethyldecahydro-4H-4,7-epoxycyclopropa[e]azulen-4-yl]methanol
• CAS No.: 136379-76-5
• Molecular Formula: C₁₅H₂₄O₂
• Molecular Weight: 236.354
• Mol file: 136379-76-5.mol

Synonyms:

Chemical Property of [(1aR,4S,4aS,7R,7aS,7bR)-1,1,7-trimethyldecahydro-4H-4,7-epoxycyclopropa[e]azulen-4-yl]methanol

Chemical Property:

• Vapor Pressure: 9.57E-05mmHg at 25°C

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(1aR,4S,4aS,7R,7aS,7bR)-1,1,7-trimethyldecahydro-4H-4,7-epoxycyclopropa[e]azulen-4-yl]methanol

There total 2 articles about [(1aR,4S,4aS,7R,7aS,7bR)-1,1,7-trimethyldecahydro-4H-4,7-epoxycyclopropa[e]azulen-4-yl]methanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Alloaromadendren-4β-ol (136458-42-9) → C15H24O2 (136379-76-5) + C15H24O2 (136458-44-1)

Guidance literature:

With Oxone; 18-crown-6 ether; silica gel; sodium hydrogencarbonate; Multistep reaction; 1.) water, acetone, CH₂Cl₂, 80 min;

DOI:10.1021/jo00023a025

Reference yield:

Alloaromadendren-4β-ol (136458-42-9) → C15H24O2 (136379-76-5) + (+/-)-Alloaromadendrane-4β,10α-diol (136458-41-8) + (1aR,4R,4aS,7R,7aS,7bR)-1,1,4,7-Tetramethyl-decahydro-cyclopropa[e]azulene-4,7-diol (136458-45-2)

Guidance literature:

With Oxone; lithium aluminium tetrahydride; 18-crown-6 ether; sodium hydrogencarbonate; Yield given. Multistep reaction. Yields of byproduct given; 1.) water, acetone, CH₂Cl₂, 80 min, 2.) ether, r.t., 17 h;

DOI:10.1021/jo00023a025

upstream raw materials:

Alloaromadendren-4β-ol