chloro(2-hydroxymethylphenyl)mercury

Base Information

• Chemical Name: chloro(2-hydroxymethylphenyl)mercury
• CAS No.: 91713-41-6
• Molecular Formula: C₇H₇ClHgO
• Molecular Weight: 343.175
• Mol file: 91713-41-6.mol

Synonyms:

Chemical Property of chloro(2-hydroxymethylphenyl)mercury

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of chloro(2-hydroxymethylphenyl)mercury

There total 1 articles about chloro(2-hydroxymethylphenyl)mercury which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

mercury dichloride + benzyl alcohol (100-51-6,185532-71-2) → chloro(2-hydroxymethylphenyl)mercury (91713-41-6)

Guidance literature:

With n-butyllithium; N,N,N',N'-tetramethylethylendiamin; In tetrahydrofuran; hexane; pentane; benzyl alcohol and TMEDA dissolved in petane, stirred, soln. n-BuLi in hexane slowly added, refluxed for 11 h under N2, suspn. decanted off, pentane added, cooled (dry ice - acetone), soln HgCl2 in THF added, warmed to room temp. (stirring); extd. (water), dry ice added, filtered, dried (vac.); elem. anal.;

DOI:10.1016/S0022-328X(00)00699-9

Reference yield: 76.0%

chloro(2-hydroxymethylphenyl)mercury (91713-41-6) + diphenylcarbazone (538-62-5) → C6H4(CH2OH)Hg[C6H5NNCONNHC6H5]

Guidance literature:

With perchlorate buffer; In tetrachloromethane; water; a soln. of the arylmercuric chloride in perchlorate buffer (pH 7) is shaken with a soln. of diphenylcarbazone in CCl4 for 20 min; the organic layer is separated, the solvent is evapd. under reduced pressure, the residue is washed, elem. anal.;

Reference yield: 74.0%

pyridinium chlorochromate + chloro(2-hydroxymethylphenyl)mercury (91713-41-6) → Hg[C6H4(CHO-2)]Cl

Guidance literature:

In dichloromethane; soln. of Hg compd. added to suspn. of chlorochromate at room temp., standed for 2 h; filtered, passed down silica column, rotary evapd., ethanol added; elem.anal.;

DOI:10.1016/S0022-328X(00)00699-9

upstream raw materials:

benzyl alcohol

Downstream raw materials:

bis(o-formylphenyl)mercury(II)