cis-2,3-epoxyheptane

Base Information

• Chemical Name: cis-2,3-epoxyheptane
• CAS No.: 149117-12-4
• Molecular Formula: C₇H₁₄O
• Molecular Weight: 114.188
• Mol file: 149117-12-4.mol

Synonyms:

Chemical Property of cis-2,3-epoxyheptane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-2,3-epoxyheptane

There total 4 articles about cis-2,3-epoxyheptane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 33.0%

(Z)-hept-2-ene (6443-92-1) → 2,3-epoxyheptane (14925-96-3,56052-93-8,56740-07-9,115667-91-9,115667-92-0,149117-08-8,149117-12-4) + n-pentyl methyl ketone (110-43-0) + heptan-3-one (106-35-4)

Guidance literature:

With trifluorormethanesulfonic acid; 2CF₃O₃S^(1-)*C₂₀H₃₂FeN₆⁽³⁺⁾; dihydrogen peroxide; at 20 ℃; for 0.0833333h; Inert atmosphere;

DOI:10.1021/ic202435r

Reference yield:

hept-2-ene (592-77-8) → 2,3-epoxyheptane (14925-96-3,56052-93-8,56740-07-9,115667-91-9,115667-92-0,149117-08-8,149117-12-4) + hept-2-en-4-one (4643-25-8) + hept-2-en-4-ol (4798-59-8)

Guidance literature:

With oxygen; γ-SiW10{Fe³⁺(OH2)}2O38^6-; In dichloromethane; acetonitrile; at 82.85 ℃; for 385h; under 760 Torr; Product distribution;

DOI:10.1002/1521-3773(20011001)40:19<3639::AID-ANIE3639>3.0.CO;2-0

Reference yield:

(Z)-hept-2-ene (6443-92-1) → 2,3-epoxyheptane (14925-96-3,56052-93-8,56740-07-9,115667-91-9,115667-92-0,149117-08-8,149117-12-4) + 2,3-Heptandiol (21508-07-6)

Guidance literature:

With [Fe(tris(2-pyridyl)amine)(triflate)2]; dihydrogen peroxide; In acetonitrile; at 22 - 25 ℃; Further Variations:; Reagents; Product distribution;

DOI:10.1021/ja029863d

upstream raw materials:

hept-2-ene

(Z)-hept-2-ene

(E)-hept-2-ene

Downstream raw materials:

heptan-3-ol

(R)-2-heptanol

(E)-hept-2-ene

(+/-)-erythro-3-ethyl-heptan-2-ol