(R,S)-2-(N,N-dimethylaminomethyl)ferrocenyl(4-bromophenyl)dimethylsilane

Base Information

Chemical Name:(R,S)-2-(N,N-dimethylaminomethyl)ferrocenyl(4-bromophenyl)dimethylsilane
CAS No.:468732-12-9
Molecular Formula:C₂₁H₂₆BrFeNSi
Molecular Weight:456.281
Hs Code.:

Synonyms:

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Chemical Property of (R,S)-2-(N,N-dimethylaminomethyl)ferrocenyl(4-bromophenyl)dimethylsilane

Chemical Property:

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Technology Process of (R,S)-2-(N,N-dimethylaminomethyl)ferrocenyl(4-bromophenyl)dimethylsilane

There total 1 articles about (R,S)-2-(N,N-dimethylaminomethyl)ferrocenyl(4-bromophenyl)dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: [α-(N,N-dimethylaminomethyl)ferrocenyl]lithium

: 18236-77-6
(4-bromophenyl)chlorodimethylsilane

: 468732-12-9
(R,S)-2-(N,N-dimethylaminomethyl)ferrocenyl(4-bromophenyl)dimethylsilane

Guidance literature:: In tetrahydrofuran; pentane; byproducts: LiCl; a suspn. of Li-compound and THF was added slowly to a stirred soln. of silane in n-pentane at -78°C, the mixt. was warmed to ambient temp., stirred overnight (Ar); evapd., dissolved in n-pentane, filtered, the solvent was removed under reduced pressure; as oil;
DOI:10.1016/S0022-328X(02)01427-4

Reference yield: 10.0%

: 468732-12-9
(R,S)-2-(N,N-dimethylaminomethyl)ferrocenyl(4-bromophenyl)dimethylsilane

: 68-12-2,33513-42-7
N,N-dimethyl-formamide

: 468732-16-3
(R,S)-2-(N,N-dimethylaminomethyl)ferrocenyl(phenyl)dimethylsilane

: 468732-15-2
(R,S)-2-(N,N-dimethylaminomethyl)ferrocenyl(4-formylphenyl)dimethylsilane

Guidance literature:: With magnesium; In tetrahydrofuran; Mg was added slowly dropwise to a stirred soln. of complex in THF, DMF was slowly added dropwise at 0°C (Ar); aq. NH4Cl was added at 0°C, the organic layer was dried (Na2SO4),evapd., NaHSO4 was addedto a soln. in diethyl ether, filtered, washed w ith hot diethyl ether, suspnd. in pentane, Na2CO3 in H2O at 0°C, dried (Na2SO), evapd.; as oil;
DOI:10.1016/S0022-328X(02)01427-4

Reference yield: 10.0%

: 468732-12-9
(R,S)-2-(N,N-dimethylaminomethyl)ferrocenyl(4-bromophenyl)dimethylsilane

: 68-12-2,33513-42-7
N,N-dimethyl-formamide

: 468732-16-3
(R,S)-2-(N,N-dimethylaminomethyl)ferrocenyl(phenyl)dimethylsilane

: 468732-15-2
(R,S)-2-(N,N-dimethylaminomethyl)ferrocenyl(4-formylphenyl)dimethylsilane

: 468732-17-4
(R,S)-2-(N,N-dimethylaminomethyl)ferrocenyl(4-carboxyphenyl)dimethylsilane

Guidance literature:: With n-butyl lithium; In pentane; byproducts: LiBr; a soln. of n-butyl lithium in pentane was added slowly dropwise to a stirred soln. of complex in pentane at -78°C, the mixt. was stirred for 40 min at -78°C, DMF was added dropwise and stirred for 60 min; treated with Et2O, filtered, aq. NH4Cl was added at 0°C, the organic layer was dried (Na2SO4), evapd., NaHSO4 was added to a soln. in ether, filtered, washed with hot ether, suspnd. in pentane, Na2CO3 in H2O at 0°C, dried (Na2SO), evapd.;
DOI:10.1016/S0022-328X(02)01427-4