(R(P),R(m),R(m),R(P))-2,2'-bis(1-naphthylphenylphosphino)-1,1'-biferrocenyl

Base Information

Chemical Name:(R(P),R(m),R(m),R(P))-2,2'-bis(1-naphthylphenylphosphino)-1,1'-biferrocenyl
CAS No.:329766-97-4
Molecular Formula:C₅₂H₄₀Fe₂P₂
Molecular Weight:838.531
Hs Code.:

Synonyms:

Suppliers and Price of (R(P),R(m),R(m),R(P))-2,2'-bis(1-naphthylphenylphosphino)-1,1'-biferrocenyl

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (R(P),R(m),R(m),R(P))-2,2'-bis(1-naphthylphenylphosphino)-1,1'-biferrocenyl

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (R(P),R(m),R(m),R(P))-2,2'-bis(1-naphthylphenylphosphino)-1,1'-biferrocenyl

There total 2 articles about (R(P),R(m),R(m),R(P))-2,2'-bis(1-naphthylphenylphosphino)-1,1'-biferrocenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

: (R(P),R(m),R(m),R(P))-(-)-2,2'-bis(1-napthylphenylphosphinoxy)-1,1'-biferrocenyl

: 329766-97-4,279243-59-3
(S(P),R(m),R(m),S(P))-(-)-2,2'-bis(1-naphthylphenylphosphino)-1,1'-biferrocenyl

: 329766-97-4,279243-59-3
(R(P),R(m),R(m),R(P))-2,2'-bis(1-naphthylphenylphosphino)-1,1'-biferrocenyl

: (R(P),R(m),R(m),S(P))-2,2'-bis(1-naphthylphenylphosphino)-1,1'-biferrocenyl

Guidance literature:: With trichlorosilane; triethylamine; BH₃*THF; In tetrahydrofuran; toluene; to suspn. diphosphine oxide in toluene Cl3SiH and Et3N were added, mixt. was heated at 140°C for 72 h, cooled and treated with NaOH soln., extd. with CH2Cl2, solvent was evapd., residue was dissolved in THF, treated with BH3*THF, and then Et2NH; react. mixt. was concd. and chromed (SiO2; CH2Cl2/hexane); elem. anal.;
DOI:10.1021/om991013s

Reference yield: 40.0%

: (R(P),R(m),R(m),R(P))-(-)-2,2'-bis(1-napthylphenylphosphinoxy)-1,1'-biferrocenyl

: 329766-97-4,279243-59-3
(S(P),R(m),R(m),S(P))-(-)-2,2'-bis(1-naphthylphenylphosphino)-1,1'-biferrocenyl

: 329766-97-4,279243-59-3
(R(P),R(m),R(m),R(P))-2,2'-bis(1-naphthylphenylphosphino)-1,1'-biferrocenyl

: (R(P),R(m),R(m),S(P))-2,2'-bis(1-naphthylphenylphosphino)-1,1'-biferrocenyl

Guidance literature:: With trichlorosilane; triethylamine; BH₃*THF; In tetrahydrofuran; toluene; to suspn. diphosphine oxide in toluene Cl3SiH and Et3N were added, mixt. was heated at 140°C for 72 h, cooled and treated with NaOH soln., extd. with CH2Cl2, solvent was evapd., residue was dissolved in THF, treated with BH3*THF, and then Et2NH; react. mixt. was concd. and chromed (SiO2; CH2Cl2/hexane); elem. anal.;
DOI:10.1021/om991013s

Reference yield: 63.0%

: 14873-63-3,15617-19-3,51921-56-3
bis(benzonitrile)dichloroplatinum(II)

: 329766-97-4,279243-59-3
(S(P),R(m),R(m),S(P))-(-)-2,2'-bis(1-naphthylphenylphosphino)-1,1'-biferrocenyl

: 279243-60-6
[(S(P),R(m),R(m),S(P))-2,2'-bis(2-biphenylphenylphosphino)-1,1'-biferrocenyl]dichloroplatinum(II)

Guidance literature:: In benzene; under Ar atm. PtCl2(PhCN)2 was dissolved in benzene and heated to 70°C, soln. diphosphine in benzene was added and mixt. was kept at reflux temp. for 1 h; mixt. was cooled, ppt. was filtered, washed with hexane, dried under vac., and recrystd. from CH2Cl2/hexane; elem. anal.;
DOI:10.1021/om991013s