trans-chloro(1,3-diisopropyltetrahydropyrimid-2-ylidene)bis(triphenylphosphine)palladium(II) chloride

Base Information

Chemical Name:trans-chloro(1,3-diisopropyltetrahydropyrimid-2-ylidene)bis(triphenylphosphine)palladium(II) chloride
CAS No.:912853-15-7
Molecular Formula:C₄₆H₅₀ClN₂P₂Pd*Cl
Molecular Weight:870.19
Hs Code.:

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Chemical Property of trans-chloro(1,3-diisopropyltetrahydropyrimid-2-ylidene)bis(triphenylphosphine)palladium(II) chloride

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Technology Process of trans-chloro(1,3-diisopropyltetrahydropyrimid-2-ylidene)bis(triphenylphosphine)palladium(II) chloride

There total 1 articles about trans-chloro(1,3-diisopropyltetrahydropyrimid-2-ylidene)bis(triphenylphosphine)palladium(II) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 28966-81-6
trans-bis(triphenylphosphine)palladium dichloride

: 223265-44-9
1,3-bis(2-propyl)-3,4,5,6-tetrahydropyrimidin-2-ylidine

: 912853-15-7
trans-chloro(1,3-diisopropyltetrahydropyrimid-2-ylidene)bis(triphenylphosphine)palladium(II) chloride

Guidance literature:: In tetrahydrofuran; inert atm., Schlenk techniques; soln. of carbene in THF added to suspn. of trans-PdCl2(PPh3)2 in THF, mixt. stirred for 3 h; evapd. under vac., residue washed with hexane, extd. with CH3CN, extractevapd. under vac., residue dissolved in CH2Cl2, pentane added, ppt. iso lated;
DOI:10.1016/j.molcata.2005.08.046

Reference yield: 93.0%

: 912853-15-7
trans-chloro(1,3-diisopropyltetrahydropyrimid-2-ylidene)bis(triphenylphosphine)palladium(II) chloride

: cis-dichloro(1,3-diisopropyltetrahydropyrimid-2-ylidene)(triphenylphosphine)palladium(II) - chloroform (4/1)

Guidance literature:: In toluene; inert atm., Schlenk techniques; soln. of trans Pd complex in toluene stirred at 120°C for 2 h; ppt. filtered off, washed with toluene, dried under vac., recrystd. fromCHCl3/n-pentane; elem. anal.;
DOI:10.1016/j.molcata.2005.08.046