C₂₇H₅₀O₄Si

Base Information

• Chemical Name: C₂₇H₅₀O₄Si
• CAS No.: 947735-90-2
• Molecular Formula: C₂₇H₅₀O₄Si
• Molecular Weight: 466.777
• Mol file: 947735-90-2.mol

Synonyms:

Chemical Property of C₂₇H₅₀O₄Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₂₇H₅₀O₄Si

There total 5 articles about C₂₇H₅₀O₄Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C28H50O5Si (947735-89-9) → C27H50O4Si (947735-90-2)

Guidance literature:

With lithium aluminium tetrahydride; In tetrahydrofuran; at 0 - 20 ℃; for 2h;

DOI:10.1016/j.bmcl.2007.05.037

Reference yield:

tert-butyl(dodec-11-ynyloxy)dimethylsilane (128098-41-9) → C27H50O4Si (947735-90-2)

Guidance literature:

Multi-step reaction with 3 steps

1: Et₃N; CuI / PdCl₂(PPh₃)2 / 80 °C

2: H₂ / Pd/C / ethanol / 24 h / 20 °C

3: LiAlH₄ / tetrahydrofuran / 2 h / 0 - 20 °C

With copper(l) iodide; lithium aluminium tetrahydride; hydrogen; triethylamine; bis-triphenylphosphine-palladium(II) chloride; palladium on activated charcoal; In tetrahydrofuran; ethanol; 1: Sonogashira cross-coupling;

DOI:10.1016/j.bmcl.2007.05.037

Reference yield:

C28H46O5Si (947735-88-8) → C27H50O4Si (947735-90-2)

Guidance literature:

Multi-step reaction with 2 steps

1: H₂ / Pd/C / ethanol / 24 h / 20 °C

2: LiAlH₄ / tetrahydrofuran / 2 h / 0 - 20 °C

With lithium aluminium tetrahydride; hydrogen; palladium on activated charcoal; In tetrahydrofuran; ethanol;

DOI:10.1016/j.bmcl.2007.05.037

upstream raw materials:

C₂₈H₅₀O₅Si

tert-butyl(dodec-11-ynyloxy)dimethylsilane

C₂₈H₄₆O₅Si

methyl 4-iodo-3,5-dimethoxybenzoate

Downstream raw materials:

C₂₇H₄₈O₄Si

C₂₉H₄₂O₄