N-(3,4-Dimethoxybenzylidene)aniline

Base Information

• Chemical Name: N-(3,4-Dimethoxybenzylidene)aniline
• CAS No.: 27895-67-6
• Molecular Formula: C15H15 N O2
• Molecular Weight: 241.29
• Hs Code.: 2925290090
• European Community (EC) Number: 665-862-8
• NSC Number: 43311
• DSSTox Substance ID: DTXSID00285956
• Nikkaji Number: J1.393.331F
• Mol file: 27895-67-6.mol

Synonyms:27895-67-6;(E)-1-(3,4-Dimethoxyphenyl)-N-phenylmethanimine;N-(3,4-Dimethoxybenzylidene)aniline;n-[(e)-(3,4-dimethoxyphenyl)methylidene]aniline;NSC43311;N-veratrylidene aniline;N-[(3,4-Dimethoxyphenyl)methylene]phenylamine;DTXSID00285956;3,4-dimethoxy-benzylidene aniline;NSC-43311;AKOS024334797

Chemical Property of N-(3,4-Dimethoxybenzylidene)aniline

Chemical Property:

• Vapor Pressure: 2.52E-05mmHg at 25°C
• Melting Point: 136-137.5 °C(Solv: ethanol (64-17-5))
• Boiling Point: 369.5°Cat760mmHg
• PKA: 3.78±0.50(Predicted)
• Flash Point: 143.8°C
• PSA: 30.82000
• Density: 1.03g/cm³
• LogP: 3.45440
• XLogP3: 3.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 4
• Exact Mass: 241.110278721
• Heavy Atom Count: 18
• Complexity: 261

Purity/Quality:

99% ^*data from raw suppliers

N-(3,4-DIMETHOXYBENZYLIDENE)ANILINE Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1=C(C=C(C=C1)C=NC2=CC=CC=C2)OC

Technology Process of N-(3,4-Dimethoxybenzylidene)aniline

There total 12 articles about N-(3,4-Dimethoxybenzylidene)aniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

3,4-dimethoxy-benzaldehyde (120-14-9) + aniline (62-53-3) → N-(3,4-dimethoxybenzylidene)aniline (27895-67-6)

Guidance literature:

In toluene; Heating;

Reference yield: 99.0%

aniline (62-53-3) + (3,4-dimethoxyphenyl)methanol (93-03-8) → N-(3,4-dimethoxybenzylidene)aniline (27895-67-6)

Guidance literature:

With potassium tert-butylate; C₁₅H₁₂Cl₂CoN₃; In toluene; at 80 ℃; for 48h; Inert atmosphere;

Reference yield: 92.0%

N-(3,4-dimethoxybenzyl)benzeneamine (82363-30-2) → N-(3,4-dimethoxybenzylidene)aniline (27895-67-6)

Guidance literature:

With oxygen; In toluene; at 100 ℃; for 20h;

DOI:10.1246/bcsj.20100300

upstream raw materials:

2,3-dimethoxy-6-(phenylimino-methyl)-benzoic acid

3,4-dimethoxy-benzaldehyde

aniline

2-methyl-3-(3,4-dimethoxyphenyl)-4-phenyl-[1,2,4]oxadiazolin-5-one

Downstream raw materials:

trans-1,2-Bis-(3,4-dimethoxy-styryl)-benzol

trans-2,3-Bis-(3,4-dimethoxy-styryl)-naphthalin

trans-1,6-Bis-(3,4-dimethoxy-styryl)-naphthalin

trans-4,4'-Bis-(3,4-dimethoxy-styryl)-biphenyl