1-(2-Methoxy-ethyl)-cyclohexa-2,5-dienecarboxylic acid

Base Information

Chemical Name:1-(2-Methoxy-ethyl)-cyclohexa-2,5-dienecarboxylic acid
CAS No.:124981-58-4
Molecular Formula:C₁₀H₁₄O₃
Molecular Weight:182.219
Hs Code.:

Synonyms:

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Chemical Property of 1-(2-Methoxy-ethyl)-cyclohexa-2,5-dienecarboxylic acid

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Technology Process of 1-(2-Methoxy-ethyl)-cyclohexa-2,5-dienecarboxylic acid

There total 1 articles about 1-(2-Methoxy-ethyl)-cyclohexa-2,5-dienecarboxylic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 65-85-0,8013-63-6
benzoic acid

: 6482-24-2
2-Bromoethyl methyl ether

: 124981-58-4
1-(2-Methoxy-ethyl)-cyclohexa-2,5-dienecarboxylic acid

Guidance literature:: DOI:10.1016/S0040-4039(00)99077-4

Reference yield: 67.0%

: 124981-58-4
1-(2-Methoxy-ethyl)-cyclohexa-2,5-dienecarboxylic acid

: 81418-58-8
2-aminoethyl-phenyl selenide

: 124981-59-5
1-(2-Methoxy-ethyl)-cyclohexa-2,5-dienecarboxylic acid (2-phenylselanyl-ethyl)-amide

Guidance literature:: With diphenylphosphoranyl azide; N-ethyl-N,N-diisopropylamine;
DOI:10.1016/S0040-4039(00)99077-4

Reference yield:

: 124981-58-4
1-(2-Methoxy-ethyl)-cyclohexa-2,5-dienecarboxylic acid

: 145387-93-5
C₂₄H₂₈N₂O₃

Guidance literature:: Multi-step reaction with 20 steps

1: 1) (PhO)2P(=O)N₃, Et₃N, pyrrolidine; 2) I₂, H₂O / 2) THF

2: 2,2'-azobisisobutyronitrile / benzene / Ambient temperature

4: 4-(N,N-dimethylamino)pyridine, pyridine

6: BBr₃

7: Swern oxidation

9: 68 percent / H₂, pyridine / BaSO₄

10: 86 percent / Ph₃P, diethyl azodicarboxylate

11: (CH₃)3SiCl, NaI / acetonitrile

12: Et₃N, 4-(N,N-dimethylamino)pyridine / CH₂Cl₂

13: 91 percent / KH, 18-crown-6, tetra-n-butylammonium iodide

14: LiOH

15: VO(acac)2, t-BuOOH / Heating

16: 86 percent / Hunig's base

17: 72 percent / CsF / dimethylformamide / Heating

18: 93 percent / 4-(N,N-dimethylamino)pyridine, Et₃N

19: 65 percent / Me₃SiCl, NaI / acetonitrile

20: 2) basic alumina / 1) Swern oxidation

With pyrrolidine; pyridine; tert.-butylhydroperoxide; dmap; aluminum oxide; lithium hydroxide; chloro-trimethyl-silane; bis(acetylacetonate)oxovanadium; 18-crown-6 ether; 2,2'-azobis(isobutyronitrile); diphenyl phosphoryl azide; water; hydrogen; iodine; boron tribromide; tetra-(n-butyl)ammonium iodide; potassium hydride; triethylamine; N-ethyl-N,N-diisopropylamine; triphenylphosphine; cesium fluoride; sodium iodide; diethylazodicarboxylate; barium sulfate; In dichloromethane; N,N-dimethyl-formamide; acetonitrile; benzene;
DOI:10.1016/S0040-4039(00)60944-9