(2S,2'S,3S,3'S)-BIBOP

Base Information

Chemical Name:(2S,2'S,3S,3'S)-BIBOP
CAS No.:1202033-17-7
Molecular Formula:C₂₂H₂₈O₂P₂
Molecular Weight:386.411
Hs Code.:

Synonyms:

Suppliers and Price of (2S,2'S,3S,3'S)-BIBOP

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Strem Chemicals
(2S,2'S,3S,3'S)-3,3'-Di-tert-butyl-2,2',3,3'-tetrahydro-2,2'-bibenzo[d][1,3]oxaphosphole, 97% (>99% ee) (2S,2'S,3S,3'S)-BIBOP
500mg
$ 735.00

Strem Chemicals
(2S,2'S,3S,3'S)-3,3'-Di-tert-butyl-2,2',3,3'-tetrahydro-2,2'-bibenzo[d][1,3]oxaphosphole, 97% (>99% ee) (2S,2'S,3S,3'S)-BIBOP 3'S)-BIBOP
25mg
$ 74.00

Strem Chemicals
(2S,2'S,3S,3'S)-3,3'-Di-tert-butyl-2,2',3,3'-tetrahydro-2,2'-bibenzo[d][1,3]oxaphosphole, 97% (>99% ee) (2S,2'S,3S,3'S)-BIBOP 3'S)-BIBOP
100mg
$ 222.00

ChemScene
(2S,2'S,3S,3'S)-BIBOP >97.0%
100mg
$ 215.00

ChemScene
(2S,2'S,3S,3'S)-BIBOP >97.0%
500mg
$ 742.00

ChemScene
(2S,2'S,3S,3'S)-BIBOP >97.0%
1g
$ 1240.00

Chemenu
(2S,2''S,3S,3''S)-3,3''-di-tert-butyl-2,2'',3,3''-tetrahydro-2,2''-bibenzo[d][1,3]oxaphosphole 95%+
5g
$ 5888.00

Chemenu
(2S,2''S,3S,3''S)-3,3''-di-tert-butyl-2,2'',3,3''-tetrahydro-2,2''-bibenzo[d][1,3]oxaphosphole 95%+
1g
$ 1472.00

Chemenu
(2S,2''S,3S,3''S)-3,3''-di-tert-butyl-2,2'',3,3''-tetrahydro-2,2''-bibenzo[d][1,3]oxaphosphole 95%+
500mg
$ 920.00

Chemenu
(2S,2''S,3S,3''S)-3,3''-di-tert-butyl-2,2'',3,3''-tetrahydro-2,2''-bibenzo[d][1,3]oxaphosphole 95%+
100mg
$ 276.00

Total 8 raw suppliers

Chemical Property of (2S,2'S,3S,3'S)-BIBOP

Chemical Property:

Boiling Point:495.5±45.0 °C(Predicted)
Storage Temp.:under inert gas (nitrogen or Argon) at 2-8°C

Purity/Quality:

95% purity >99% ee ^*data from raw suppliers

(2S,2'S,3S,3'S)-3,3'-Di-tert-butyl-2,2',3,3'-tetrahydro-2,2'-bibenzo[d][1,3]oxaphosphole, 97% (>99% ee) (2S,2'S,3S,3'S)-BIBOP ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (2S,2'S,3S,3'S)-BIBOP

There total 9 articles about (2S,2'S,3S,3'S)-BIBOP which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 1202033-09-7
(2S,2'S,3R,3'R)-3,3'-di-tert-butyl-2,2',3,3'-tetrahydro-2,2'-bibenzo[d][1,3]oxaphosphole bisoxide

: 1202033-17-7,1610785-35-7
BIBOP

Guidance literature:: With trichlorosilane; triethylamine; In toluene; at 80 ℃; for 12h; Inert atmosphere;
DOI:10.1021/ol9025815

Reference yield:

: 151-10-0
1,3-Dimethoxybenzene

: 1202033-17-7,1610785-35-7
BIBOP

Guidance literature:: Multi-step reaction with 9 steps

1.1: n-butyllithium / tetrahydrofuran / 1.5 h / 0 °C

1.2: 1.5 h / 25 °C

1.3: 0.67 h / 0 - 25 °C

2.1: N,N,N,N,-tetramethylethylenediamine; n-butyllithium / hexane; tetrahydrofuran / 1.17 h / -78 °C

2.2: 1.5 h / -78 - 25 °C

3.1: boron tribromide / 1,2-dichloro-ethane / 2.5 h / 0 - 60 °C

3.2: 2 h / 60 °C

4.1: triethylamine / dichloromethane / 2.58 h / 0 - 25 °C

5.1: potassium hydroxide; water / ethanol / 2 h / 25 °C

5.2: 0 °C / pH 4

6.1: triethylamine / dichloromethane / 2 h / 0 - 25 °C

7.1: triethylamine; hydrogen / 20% palladium hydroxide on carbon / ethyl acetate / 12 h / 25 °C / 5171.62 Torr

8.1: lithium diisopropyl amide / n-heptane; chlorobenzene; tetrahydrofuran / 1 h / -78 °C

8.2: 2 h / -78 - 25 °C

9.1: triethylamine; trichlorosilane / toluene / 12 h / 25 - 80 °C / Inert atmosphere

With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; trichlorosilane; water; hydrogen; boron tribromide; triethylamine; potassium hydroxide; lithium diisopropyl amide; 20% palladium hydroxide on carbon; In tetrahydrofuran; ethanol; hexane; n-heptane; dichloromethane; ethyl acetate; 1,2-dichloro-ethane; chlorobenzene; toluene;

Reference yield:

: 1202032-93-6
tert-butyl(2,6-dimethoxyphenyl)(iodomethyl)phosphine oxide

: 1202033-17-7,1610785-35-7
BIBOP

Guidance literature:: Multi-step reaction with 7 steps

1.1: boron tribromide / 1,2-dichloro-ethane / 2.5 h / 0 - 60 °C

1.2: 2 h / 60 °C

2.1: triethylamine / dichloromethane / 2.58 h / 0 - 25 °C

3.1: potassium hydroxide; water / ethanol / 2 h / 25 °C

3.2: 0 °C / pH 4

4.1: triethylamine / dichloromethane / 2 h / 0 - 25 °C

5.1: triethylamine; hydrogen / 20% palladium hydroxide on carbon / ethyl acetate / 12 h / 25 °C / 5171.62 Torr

6.1: lithium diisopropyl amide / n-heptane; chlorobenzene; tetrahydrofuran / 1 h / -78 °C

6.2: 2 h / -78 - 25 °C

7.1: triethylamine; trichlorosilane / toluene / 12 h / 25 - 80 °C / Inert atmosphere

With trichlorosilane; water; hydrogen; boron tribromide; triethylamine; potassium hydroxide; lithium diisopropyl amide; 20% palladium hydroxide on carbon; In tetrahydrofuran; ethanol; n-heptane; dichloromethane; ethyl acetate; 1,2-dichloro-ethane; chlorobenzene; toluene;