(η⁵-C₅H₄PPh₂)Re(CO)₂PMe₃

Base Information

• Chemical Name: (η⁵-C₅H₄PPh₂)Re(CO)₂PMe₃
• CAS No.: 1241904-55-1
• Molecular Formula: C₂₂H₂₃O₂P₂Re
• Molecular Weight: 567.578

Synonyms:

Chemical Property of (η⁵-C₅H₄PPh₂)Re(CO)₂PMe₃

Chemical Property:

Purity/Quality:

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Technology Process of (η⁵-C₅H₄PPh₂)Re(CO)₂PMe₃

There total 1 articles about (η⁵-C₅H₄PPh₂)Re(CO)₂PMe₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

tricarbonyl(η5-diphenylphosphinocyclopentadienyl)rhenium + trimethylphosphane (594-09-2) → (η5-C5H4PPh2)Re(CO)2PMe3 (1241904-55-1)

Guidance literature:

In tetrahydrofuran; Irradiation (UV/VIS); under N2; a soln. of Re-contg. compd. (0.173 mmol) in THF was purged with N2 for 5 min; PMe3 (0.30 mmol) addn.; irradn. at 300 nm; IR spectra monitoring (ca. 2 h); the soln. was evapd. to dryness; silicagel column, elution with with a hexane/ CH2Cl2 3:1 mixt.; elem. anal.;

DOI:10.1039/b927265h

Reference yield: 100.0%

borane-THF (14044-65-6) + (η5-C5H4PPh2)Re(CO)2PMe3 (1241904-55-1) → C22H26BO2P2Re

Guidance literature:

In tetrahydrofuran;

DOI:10.1016/j.inoche.2017.01.017

Reference yield: 87.0%

bis(benzonitrile)palladium(II) dichloride (15617-18-2,39958-10-6,14220-64-5) + (η5-C5H4PPh2)Re(CO)2PMe3 (1241904-55-1) + acetonitrile (75-05-8,26809-02-9) → (CO)2(PMe3)(η5-C5H4PPh2)RePdCl2*2(acetonitrile)

Guidance literature:

In chloroform; under N2; Re-contg. compd. (0.10 mmol) was dissolved in dry chloroform at room temp.; solid Pd-contg. compd. (0.100 mmol) was added; the mixt. was stirred and refluxed for 6 h; the solvent was evapd. to dryness; the solid was dissolved in CH3CN and allowed to crystallize at low temp.; elem. anal.;

DOI:10.1039/b927265h

upstream raw materials:

trimethylphosphane

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