(5,15-di(pyridin-4-yl)-10,20-bis(pentafluorophenyl))porphyrinato manganese (III) chloride

Base Information

• Chemical Name: (5,15-di(pyridin-4-yl)-10,20-bis(pentafluorophenyl))porphyrinato manganese (III) chloride
• CAS No.: 1280658-37-8
• Molecular Formula: C₄₂H₁₆ClF₁₀MnN₆
• Molecular Weight: 885.004
• Mol file: 1280658-37-8.mol

Synonyms:

Chemical Property of (5,15-di(pyridin-4-yl)-10,20-bis(pentafluorophenyl))porphyrinato manganese (III) chloride

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of (5,15-di(pyridin-4-yl)-10,20-bis(pentafluorophenyl))porphyrinato manganese (III) chloride

There total 1 articles about (5,15-di(pyridin-4-yl)-10,20-bis(pentafluorophenyl))porphyrinato manganese (III) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

(5,15-di(pyridin-4-yl)-10,20-bis(pentafluorophenyl))porphyrin → (5,15-di(pyridin-4-yl)-10,20-bis(pentafluorophenyl))porphyrinato manganese (III) chloride (1280658-37-8)

Guidance literature:

(5,15-di(pyridin-4-yl)-10,20-bis(pentafluorophenyl))porphyrin; With manganese (II) acetate tetrahydrate; acetic acid; at 170 ℃; for 1h;

With lithium chloride; for 0.5h;

DOI:10.1021/ja111042f

Reference yield:

zinc(II) nitrate hexahydrate + 4,4′,4″,4?-(iron(III)porphine-5,10,15,20-tetrayl)-tetrakis(benzoic acid) chloride + (5,15-di(pyridin-4-yl)-10,20-bis(pentafluorophenyl))porphyrinato manganese (III) chloride (1280658-37-8) → [Zn2(FeCl)(MnCl)(C20H8N4(C6H4CO2)4)(5,15-di(4-pyridyl)-10,20-bis(pentafluorophenyl)porphyrinato)]

Guidance literature:

With HNO₃; In ethanol; N,N-dimethyl-formamide; static heating of FeCl(C20H8N4(C6H4CO2H)4) and Zn salt in DMF at 80°C for 2 h, addn. of HNO3 in EtOH and MnCl(C20H8N4(C6F5)2(C5H4N)2), heating at 80°C for 20 h;

DOI:10.1021/ja111042f

Reference yield:

zinc(II) nitrate hexahydrate + 5,10,15,20-tetra(4-carboxyphenyl)porphyrin + (5,15-di(pyridin-4-yl)-10,20-bis(pentafluorophenyl))porphyrinato manganese (III) chloride (1280658-37-8) → [Zn3(MnCl)(C20H8N4(C6H4CO2)4)(5,15-di(4-pyridyl)-10,20-bis(pentafluorophenyl)porphyrinato)]

Guidance literature:

With HNO₃; In ethanol; N,N-dimethyl-formamide; static heating of C20H10N4(C6H4CO2H)4 and Zn salt in DMF at 80°C for 2 h, addn. of HNO3 in EtOH and Mn complex, heating at 80°C for 20 h;

DOI:10.1021/ja111042f