[Cu₈(2-methylimidazolate)8]*(benzene)

Base Information

• Chemical Name: [Cu₈(2-methylimidazolate)8]*(benzene)
• CAS No.: 791072-58-7
• Molecular Formula: C₆H₆*C₃₂H₄₀Cu₈N₁₆
• Molecular Weight: 1235.26
• Mol file: 791072-58-7.mol

Synonyms:

Chemical Property of [Cu₈(2-methylimidazolate)8]*(benzene)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of [Cu₈(2-methylimidazolate)8]*(benzene)

There total 2 articles about [Cu₈(2-methylimidazolate)8]*(benzene) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 25.0%

2-methylimidazole (693-98-1) + copper(II) nitrate trihydrate + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → [Cu8(2-methylimidazolate)8]*(benzene) (791072-58-7)

Guidance literature:

With aq. NH₃; In water; benzene; High Pressure; mixt. of Cu salt, 2-methylimidazole, C6H6, aq. NH3 was stirred for 15 min in air; transferred and sealed in Teflon-lined vessel; heated in oven to 160°C for 80 h; cooled to room temp. at a rate of 5°C/h; filtered; washed (EtOH); dried under N2; identified by X-ray diffraction; elem. anal.;

DOI:10.1021/ic300083k

Reference yield:

2-methylimidazole (693-98-1) + (Cu(NH3)2)(1+)*OH(1-)=(Cu(NH3)2)OH + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → [Cu8(2-methylimidazolate)8]*(benzene) (791072-58-7)

Guidance literature:

With aq. NH₃; In methanol; water; benzene; under N2 atm.; prepn. by pouring soln. of Cu(NH3)2(OH) in aq. NH3/MeOH into soln. of 2-methylimidazole in MeOH/C6H6 with rapid stirring; filtered; washed; dried under N2 atm.;

DOI:10.1021/ic300083k

upstream raw materials:

2-methylimidazole

benzene