η4-1,5-cyclooctadienebis(triphenylphosphine)rhodium(I) bis((trifluoromethyl)sulfonyl)amide

Base Information

Chemical Name:η4-1,5-cyclooctadienebis(triphenylphosphine)rhodium(I) bis((trifluoromethyl)sulfonyl)amide
CAS No.:1043632-56-9
Molecular Formula:C₂F₆NO₄S₂*C₄₄H₄₂P₂Rh
Molecular Weight:1015.82
Hs Code.:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of η4-1,5-cyclooctadienebis(triphenylphosphine)rhodium(I) bis((trifluoromethyl)sulfonyl)amide

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Technology Process of η4-1,5-cyclooctadienebis(triphenylphosphine)rhodium(I) bis((trifluoromethyl)sulfonyl)amide

There total 1 articles about η4-1,5-cyclooctadienebis(triphenylphosphine)rhodium(I) bis((trifluoromethyl)sulfonyl)amide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: chloro(1,5-cyclooctadiene)rhodium(I) dimer

: 603-35-0
triphenylphosphine

: 90076-65-6
bis(trifluoromethane)sulfonimide lithium

: 1043632-56-9
η4-1,5-cyclooctadienebis(triphenylphosphine)rhodium(I) bis((trifluoromethyl)sulfonyl)amide

Guidance literature:: In dichloromethane; water; (N2); using Schlenk techniques; dissolving of di-μ-chlorobis(η4-1,5-cyclooctadiene)dirhodium in CH2Cl2; addn. of soln. of Li((CF3SO2)2N) in H2O; addn. of PPh3 under vigorous stirring; stirring for 2 h at room temp.; sepn. of phase; removal of water layer with syringe; washing of org. phase with H2O; concn. with stream of N2; slow addn. of isopropanol; pptn.,addn. of hexanes; crystn., filtration, washing with hexanes; drying in vac., elem. anal.;
DOI:10.1016/j.jorganchem.2008.04.017