TaCl(η(5)-C5Me5)(N(2,6-Me2C6H3))(η(2)-C(i-Pr)=N(2,6-Me2C6H3))

Base Information

• Chemical Name: TaCl(η(5)-C5Me5)(N(2,6-Me2C6H3))(η(2)-C(i-Pr)=N(2,6-Me2C6H3))
• CAS No.: 212568-94-0
• Molecular Formula: C₃₀H₄₀ClN₂Ta
• Molecular Weight: 645.062
• Mol file: 212568-94-0.mol

Synonyms:

Chemical Property of TaCl(η(5)-C5Me5)(N(2,6-Me2C6H3))(η(2)-C(i-Pr)=N(2,6-Me2C6H3))

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of TaCl(η(5)-C5Me5)(N(2,6-Me2C6H3))(η(2)-C(i-Pr)=N(2,6-Me2C6H3))

There total 1 articles about TaCl(η(5)-C5Me5)(N(2,6-Me2C6H3))(η(2)-C(i-Pr)=N(2,6-Me2C6H3)) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

(η(5)-pentamethylcyclopentadienyl)TaCl2(NC6H3Me2-2,6) + 2,6-dimethylphenyl isonitrile (119072-54-7,2769-71-3) + isopropylmagnesium chloride (1068-55-9) → TaCl(η(5)-C5Me5)(N(2,6-Me2C6H3))(η(2)-C(i-Pr)=N(2,6-Me2C6H3)) (212568-94-0)

Guidance literature:

In toluene; Ar-atmosphere; dropwise addn. of 1 equiv. of Mg-compd. to mixt. of Ta-complex and isonitrile, stirring (room temp., 1 h); filtration, solvent removal (vac.), washing (hexane); elem. anal.;

DOI:10.1016/S0022-328X(98)00570-1

upstream raw materials:

2,6-dimethylphenyl isonitrile

isopropylmagnesium chloride