3,5-Dinitro-benzoic acid 2-hydroxy-3-[(2R,3R,3aS,9aR)-2-(4-hydroxy-2-oxo-2H-pyrimidin-1-yl)-5,5,7,7-tetraisopropyl-tetrahydro-1,4,6,8-tetraoxa-5,7-disila-cyclopentacycloocten-3-yl]-propyl ester

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Chemical Name:3,5-Dinitro-benzoic acid 2-hydroxy-3-[(2R,3R,3aS,9aR)-2-(4-hydroxy-2-oxo-2H-pyrimidin-1-yl)-5,5,7,7-tetraisopropyl-tetrahydro-1,4,6,8-tetraoxa-5,7-disila-cyclopentacycloocten-3-yl]-propyl ester
CAS No.:199480-56-3
Molecular Formula:C₃₁H₄₆N₄O₁₃Si₂
Molecular Weight:738.896
Hs Code.:

3,5-Dinitro-benzoic acid 2-hydroxy-3-[(2R,3R,3aS,9aR)-2-(4-hydroxy-2-oxo-2H-pyrimidin-1-yl)-5,5,7,7-tetraisopropyl-tetrahydro-1,4,6,8-tetraoxa-5,7-disila-cyclopentacycloocten-3-yl]-propyl ester

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Chemical Property of 3,5-Dinitro-benzoic acid 2-hydroxy-3-[(2R,3R,3aS,9aR)-2-(4-hydroxy-2-oxo-2H-pyrimidin-1-yl)-5,5,7,7-tetraisopropyl-tetrahydro-1,4,6,8-tetraoxa-5,7-disila-cyclopentacycloocten-3-yl]-propyl ester

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Technology Process of 3,5-Dinitro-benzoic acid 2-hydroxy-3-[(2R,3R,3aS,9aR)-2-(4-hydroxy-2-oxo-2H-pyrimidin-1-yl)-5,5,7,7-tetraisopropyl-tetrahydro-1,4,6,8-tetraoxa-5,7-disila-cyclopentacycloocten-3-yl]-propyl ester

There total 1 articles about 3,5-Dinitro-benzoic acid 2-hydroxy-3-[(2R,3R,3aS,9aR)-2-(4-hydroxy-2-oxo-2H-pyrimidin-1-yl)-5,5,7,7-tetraisopropyl-tetrahydro-1,4,6,8-tetraoxa-5,7-disila-cyclopentacycloocten-3-yl]-propyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1-((2R,3R,3aS,9aR)-3-Allyl-5,5,7,7-tetraisopropyl-tetrahydro-1,4,6,8-tetraoxa-5,7-disila-cyclopentacycloocten-2-yl)-4-hydroxy-1H-pyrimidin-2-one

: 199480-56-3
3,5-Dinitro-benzoic acid 2-hydroxy-3-[(2R,3R,3aS,9aR)-2-(4-hydroxy-2-oxo-2H-pyrimidin-1-yl)-5,5,7,7-tetraisopropyl-tetrahydro-1,4,6,8-tetraoxa-5,7-disila-cyclopentacycloocten-3-yl]-propyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 99.6 percent / N-methylmorpholine N-oxide, OsO₄ / acetone; H₂O / 1.5 h

2: 64 percent / pyridine / 2 h

With pyridine; osmium(VIII) oxide; 4-methylmorpholine N-oxide; In water; acetone;
DOI:10.1021/jo9614607

Reference yield:

: 199480-56-3
3,5-Dinitro-benzoic acid 2-hydroxy-3-[(2R,3R,3aS,9aR)-2-(4-hydroxy-2-oxo-2H-pyrimidin-1-yl)-5,5,7,7-tetraisopropyl-tetrahydro-1,4,6,8-tetraoxa-5,7-disila-cyclopentacycloocten-3-yl]-propyl ester

: 185141-89-3
Acetic acid 1-acetoxymethyl-2-[(2R,3R,4S,5R)-5-[bis-(4-methoxy-phenyl)-phenyl-methoxymethyl]-4-hydroxy-2-(4-hydroxy-2-oxo-2H-pyrimidin-1-yl)-tetrahydro-furan-3-yl]-ethyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) NH₃, MeOH, 2.) pyridine / 1.) 16 h, 2.) 20 h

2: 81 percent / Et₃N*HF / tetrahydrofuran

3: 94 percent / pyridine / CH₂Cl₂ / 1 h

With pyridine; methanol; ammonia; triethylamine hydrofluoride; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo9614607

Reference yield:

: 199480-56-3
3,5-Dinitro-benzoic acid 2-hydroxy-3-[(2R,3R,3aS,9aR)-2-(4-hydroxy-2-oxo-2H-pyrimidin-1-yl)-5,5,7,7-tetraisopropyl-tetrahydro-1,4,6,8-tetraoxa-5,7-disila-cyclopentacycloocten-3-yl]-propyl ester

: 185141-92-8
Acetic acid 1-acetoxymethyl-2-[(2R,3R,4S,5R)-5-[bis-(4-methoxy-phenyl)-phenyl-methoxymethyl]-4-[(2-cyano-ethoxy)-diisopropylamino-phosphanyloxy]-2-(4-hydroxy-2-oxo-2H-pyrimidin-1-yl)-tetrahydro-furan-3-yl]-ethyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) NH₃, MeOH, 2.) pyridine / 1.) 16 h, 2.) 20 h

2: 81 percent / Et₃N*HF / tetrahydrofuran

3: 94 percent / pyridine / CH₂Cl₂ / 1 h

4: 73 percent / diisopropylammonium tetrazolide / CH₂Cl₂ / 16 h

With pyridine; methanol; N,N-diisopropylamine tetrazolide; ammonia; triethylamine hydrofluoride; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo9614607