(C₄H₉)3SnC(CH₃)(C₂H₅)SO₂C₆H₅

Base Information

• Chemical Name: (C₄H₉)3SnC(CH₃)(C₂H₅)SO₂C₆H₅
• CAS No.: 895579-42-7
• Molecular Formula: C₂₂H₄₀O₂SSn
• Molecular Weight: 487.334
• Mol file: 895579-42-7.mol

Synonyms:

Chemical Property of (C₄H₉)3SnC(CH₃)(C₂H₅)SO₂C₆H₅

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of (C₄H₉)3SnC(CH₃)(C₂H₅)SO₂C₆H₅

There total 1 articles about (C₄H₉)3SnC(CH₃)(C₂H₅)SO₂C₆H₅ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

(±)-(sec-butylsulfonyl)benzene (34009-06-8) + tributyltin chloride (1461-22-9) → (C4H9)3SnC(CH3)(C2H5)SO2C6H5 (895579-42-7)

Guidance literature:

With n-butyllithium; In tetrahydrofuran; hexane; (N2); std. Schlenk technique; soln. of BuLi in hexane was added dropwiseto stirred soln. of sulfone in THF at -78°C; stirred at -78.degr ee.C for 15 min; Bu3SnCl was added at -78°C; stirred at room temp. for 18 h; H2O added; extd. (ether); org. phase dried (Na2SO4); solvent removed (vac.); chromd. (centrifugal thin layer, pentane/Et2O); elem. anal.;

DOI:10.1016/j.jorganchem.2005.12.048

upstream raw materials:

(±)-(sec-butylsulfonyl)benzene

tributyltin chloride