bis(ethylenebis(diphenylphosphine))(2-n-butyldiazenido-N)iodomolybdenum

Base Information

Chemical Name:bis(ethylenebis(diphenylphosphine))(2-n-butyldiazenido-N)iodomolybdenum
CAS No.:75400-23-6
Molecular Formula:C₅₆H₅₇IMoN₂P₄
Molecular Weight:1104.82
Hs Code.:

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Chemical Property of bis(ethylenebis(diphenylphosphine))(2-n-butyldiazenido-N)iodomolybdenum

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Technology Process of bis(ethylenebis(diphenylphosphine))(2-n-butyldiazenido-N)iodomolybdenum

There total 1 articles about bis(ethylenebis(diphenylphosphine))(2-n-butyldiazenido-N)iodomolybdenum which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%

: 542-69-8
1-iodo-butane

: 50495-19-7,25145-64-6,41700-58-7
[Mo(N₂)2(1,2-bis(diphenylphosphino)ethane)2]

: 75400-23-6
bis(ethylenebis(diphenylphosphine))(2-n-butyldiazenido-N)iodomolybdenum

Guidance literature:: In benzene; Irradiation (UV/VIS); under N2 atm. n-butyl iodide added to soln. Mo(N2)2(dppe)2 in benzene and irradiated (3 100-W light bulbs) at room temp. for 7 h with stirring; soln. filtered, volume reduced, methanol added, allowed to stand for 3 h, soln. filtered, solvent evapd. to dryness, solid dissolved in 2-propanol and soln. allowed to stand overnight, crystals filtered off, washed with 2-propanol and dried; elem. anal.;
DOI:10.1021/ic50215a007

Reference yield:

: 75400-23-6
bis(ethylenebis(diphenylphosphine))(2-n-butyldiazenido-N)iodomolybdenum

: Mo(NCS)(N₂C₄H₉)(dppe)2

Guidance literature:: With potassium thioacyanate; In acetone; benzene; under N2 atm. MoI(N2C4H9)(dppe)2 react with KNCS in C6H6-acetone at 25°C;
DOI:10.1021/ic50215a007

Reference yield:

: 75400-23-6
bis(ethylenebis(diphenylphosphine))(2-n-butyldiazenido-N)iodomolybdenum

: Mo(N₃)(N₂C₄H₉)(dppe)2

Guidance literature:: With sodium azide; 18-crown-6 ether; In ethanol; benzene; under N2 atm. MoI(N2C4H9)(dppe)2 react with NaN3 in C6H6-ethanol in thepresence 18-crown-6 ether at 25°C;
DOI:10.1021/ic50215a007