cis,cis-(C₆H₉(NHCH₂C₆H₄-o-PPh₂)3

Base Information

• Chemical Name: cis,cis-(C₆H₉(NHCH₂C₆H₄-o-PPh₂)3
• CAS No.: 1195006-37-1
• Molecular Formula: C₆₃H₆₀N₃P₃
• Molecular Weight: 952.111
• Mol file: 1195006-37-1.mol

Synonyms:

Chemical Property of cis,cis-(C₆H₉(NHCH₂C₆H₄-o-PPh₂)3

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of cis,cis-(C₆H₉(NHCH₂C₆H₄-o-PPh₂)3

There total 1 articles about cis,cis-(C₆H₉(NHCH₂C₆H₄-o-PPh₂)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

cis,cis-C6H9(N=CHC6H4(PPh2))3 → cis,cis-(C6H9(NHCH2C6H4-o-PPh2)3 (1195006-37-1)

Guidance literature:

With lithium aluminium tetrahydride; In tetrahydrofuran; for 48h;

DOI:10.1039/c0dt00005a

Reference yield: 98.0%

cis,cis-(C6H9(NHCH2C6H4-o-PPh2)3 (1195006-37-1) + trimethylaluminum (75-24-1) → [cis,cis-(C6H9(NHCH2C6H4-o-PPh2)2-κN)2(NHCH2C6H4-o-PPh2-κN)]AlMe (1233956-00-7)

Guidance literature:

In toluene; byproducts: CH4; (N2); ligand (1 equiv.) and AlMe3 (1 equiv.) were mixed in, heated at 100°C for 48 h; evapd. in vac., elem. anal.;

DOI:10.1039/c0dt00005a

Reference yield: 78.0%

tris(norbornene)platinum(0) (57158-98-2) + cis,cis-(C6H9(NHCH2C6H4-o-PPh2)3 (1195006-37-1) → [Pt(cis,cis-C6H9(NHCH2C6H4(PPh2))3)]n (1195006-40-6)

Guidance literature:

In toluene; (under N2, Schlenk); ligand dissolved in toluene, soln. of Pt-complex intoluene added, stirred for 12 h; filtered, dried under vac., washed with pentane; elem. anal.;

DOI:10.1039/b907737e

Downstream raw materials:

[Pt(cis,cis-C₆H₉(NHCH₂C₆H₄(PPh₂))3)]n

[cis,cis-(C6H9(NHCH2C6H4-o-PPh2)2-κN)2(NHCH2C6H4-o-PPh2-κN)]AlMe

[cis,cis-(C6H9(NHCH2C6H4-o-PPh2)3-κ5μ2 N]Al2Me3