methyl 6-O-(6'-O-benzoyl-6'-O-(6''-O-benzoyl-4''-benzyl-2'',3''-dideoxy-α-D-erythro-hex-2-enopyranosyl)-2',3'-dideoxy-α-D-glycelohex-2'-enopyranos-4'-ulosyl)-2,3,4-tri-O-benzyl-α-D-glucopyranoside

Base Information

• Chemical Name: methyl 6-O-(6'-O-benzoyl-6'-O-(6''-O-benzoyl-4''-benzyl-2'',3''-dideoxy-α-D-erythro-hex-2-enopyranosyl)-2',3'-dideoxy-α-D-glycelohex-2'-enopyranos-4'-ulosyl)-2,3,4-tri-O-benzyl-α-D-glucopyranoside
• CAS No.: 1221721-01-2
• Molecular Formula: C₅₄H₅₈O₁₃
• Molecular Weight: 915.047
• Mol file: 1221721-01-2.mol

Synonyms:

Chemical Property of methyl 6-O-(6'-O-benzoyl-6'-O-(6''-O-benzoyl-4''-benzyl-2'',3''-dideoxy-α-D-erythro-hex-2-enopyranosyl)-2',3'-dideoxy-α-D-glycelohex-2'-enopyranos-4'-ulosyl)-2,3,4-tri-O-benzyl-α-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl 6-O-(6'-O-benzoyl-6'-O-(6''-O-benzoyl-4''-benzyl-2'',3''-dideoxy-α-D-erythro-hex-2-enopyranosyl)-2',3'-dideoxy-α-D-glycelohex-2'-enopyranos-4'-ulosyl)-2,3,4-tri-O-benzyl-α-D-glucopyranoside

There total 1 articles about methyl 6-O-(6'-O-benzoyl-6'-O-(6''-O-benzoyl-4''-benzyl-2'',3''-dideoxy-α-D-erythro-hex-2-enopyranosyl)-2',3'-dideoxy-α-D-glycelohex-2'-enopyranos-4'-ulosyl)-2,3,4-tri-O-benzyl-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methyl 2,3,4-tri-O-benzyl-D-glucopyranoside (53008-65-4,641635-63-4) + 6-O-(6'-O-benzoyl-4'-O-benzyl-2',3'-dideoxy-α-D-erythro-hexopyranosyl)-2,3-dideoxy-α-D-glycelo-hex-2-enopyranos-4-ulosyl acetate (1221720-97-3) → methyl 6-O-(6'-O-benzoyl-6'-O-(6''-O-benzoyl-4''-benzyl-2'',3''-dideoxy-α-D-erythro-hex-2-enopyranosyl)-2',3'-dideoxy-α-D-glycelohex-2'-enopyranos-4'-ulosyl)-2,3,4-tri-O-benzyl-α-D-glucopyranoside (1221721-01-2) + methyl 6-O-(6'-O-benzoyl-6'-O-(6''-O-benzoyl-4''-benzyl-2'',3''-dideoxy-α-D-erythro-hex-2-enopyranosyl)-2',3'-dideoxy-β-D-glycelohex-2'-enopyranos-4'-ulosyl)-2,3,4-tri-O-benzyl-α-D-glucopyranoside (1221721-03-4)

Guidance literature:

methyl 2,3,4-tri-O-benzyl-D-glucopyranoside; 6-O-(6'-O-benzoyl-4'-O-benzyl-2',3'-dideoxy-α-D-erythro-hexopyranosyl)-2,3-dideoxy-α-D-glycelo-hex-2-enopyranos-4-ulosyl acetate; In toluene; at 25 ℃; for 0.5h; Molecular sieve;

With trimethylsilyl trifluoromethanesulfonate; In toluene; at -35 ℃; for 0.5h; optical yield given as %de; chemoselective reaction;

DOI:10.1039/b925587g

upstream raw materials:

methyl 2,3,4-tri-O-benzyl-D-glucopyranoside

6-O-(6'-O-benzoyl-4'-O-benzyl-2',3'-dideoxy-α-D-erythro-hexopyranosyl)-2,3-dideoxy-α-D-glycelo-hex-2-enopyranos-4-ulosyl acetate