cis-1-dimethylarsino-2-diphenylarsinoethylene

Base Information

• Chemical Name: cis-1-dimethylarsino-2-diphenylarsinoethylene
• CAS No.: 60797-43-5
• Molecular Formula: C₁₆H₁₈As₂
• Molecular Weight: 360.162
• Mol file: 60797-43-5.mol

Synonyms:

Chemical Property of cis-1-dimethylarsino-2-diphenylarsinoethylene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-1-dimethylarsino-2-diphenylarsinoethylene

There total 1 articles about cis-1-dimethylarsino-2-diphenylarsinoethylene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ cis-1-dimethylarsino-2-diphenylarsinoethylene (60797-43-5)

Guidance literature:

Na(AsMe2), cis-2-Chlorvinyldiphenylarsin;

Reference yield: 85.0%

cis-1-dimethylarsino-2-diphenylarsinoethylene (60797-43-5) + sodium tetraphenyl borate (143-66-8) + nickel dibromide (13462-88-9) → [Ni(cis-1-dimethylarsino-2-diphenylarsinoethylene)2Br]BPh4 (58466-34-5)

Guidance literature:

In ethanol; acetone; N2-atmosphere; addn. of NiBr2 (in EtOH) to 2 equiv. of ligand (in Me2CO), stirring for 20 min, pptn. on addn. of 1 equiv. NaBPh4 (in EtOH); recrystn. (CH2Cl2/EtOH); elem. anal.;

DOI:10.1016/S0020-1693(00)91708-0

Reference yield: 60.0%

nickel(II) perchlorate hexahydrate + cis-1-dimethylarsino-2-diphenylarsinoethylene (60797-43-5) → [Ni(cis-1-dimethylarsino-2-diphenylarsinoethylene)2](ClO4)2

Guidance literature:

In ethanol; acetone; N2-atmosphere; dropwise addn. of Ni(ClO4)2 (in EtOH) to 2 equiv. of ligand (in refluxing Me2CO); crystn. on cooling; elem. anal.;

DOI:10.1016/S0020-1693(00)91708-0

Downstream raw materials:

[Ni(cis-1-dimethylarsino-2-diphenylarsinoethylene)2Cl]Cl

[Ni(cis-1-dimethylarsino-2-diphenylarsinoethylene)2I]I

[Ni(cis-1-dimethylarsino-2-diphenylarsinoethylene)2NCS]BPh₄

[Ni(cis-1-dimethylarsino-2-diphenylarsinoethylene)2Br]BPh₄