Technology Process of C40H38O16
There total 6 articles about C40H38O16 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 2 steps
1: palladium on activated charcoal; hydrogen / tetrahydrofuran; methanol; dichloromethane / 24 h / 20 °C
2: iron(II) ammonium sulfate; recombinant N-terminally His6-tagged Vitis vinifera cabernet sauvignon leucoanthocyanidin dioxygenase; α-ketoglutaric acid; sodium L-ascorbate; bovine catalase / 1 h / 30 °C / pH 6 / aq. phosphate buffer; Enzymatic reaction
With
iron(II) ammonium sulfate; α-ketoglutaric acid; palladium on activated charcoal; recombinant N-terminally His6-tagged Vitis vinifera cabernet sauvignon leucoanthocyanidin dioxygenase; hydrogen; sodium L-ascorbate; bovine catalase;
In
tetrahydrofuran; methanol; dichloromethane;
DOI:10.1002/cbic.201100044
- Guidance literature:
-
Multi-step reaction with 6 steps
1: potassium carbonate / N,N-dimethyl-formamide / 48 h / 20 °C
2: sodium hydride / N,N-dimethyl-formamide / 6 h / 0 °C
3: trichlorophosphate / 19 h / 20 - 75 °C
4: sodium hydride / N,N-dimethyl-formamide / 15 h / 20 °C
5: palladium on activated charcoal; hydrogen / tetrahydrofuran; methanol; dichloromethane / 24 h / 20 °C
6: iron(II) ammonium sulfate; recombinant N-terminally His6-tagged Vitis vinifera cabernet sauvignon leucoanthocyanidin dioxygenase; α-ketoglutaric acid; sodium L-ascorbate; bovine catalase / 1 h / 30 °C / pH 6 / aq. phosphate buffer; Enzymatic reaction
With
iron(II) ammonium sulfate; α-ketoglutaric acid; palladium on activated charcoal; recombinant N-terminally His6-tagged Vitis vinifera cabernet sauvignon leucoanthocyanidin dioxygenase; hydrogen; sodium hydride; potassium carbonate; sodium L-ascorbate; bovine catalase; trichlorophosphate;
In
tetrahydrofuran; methanol; dichloromethane; N,N-dimethyl-formamide;
3: Vilsmeier-Haack reaction / 4: Horner-Wadsworth-Emmons olefination;
DOI:10.1002/cbic.201100044
- Guidance literature:
-
Multi-step reaction with 5 steps
1: sodium hydride / N,N-dimethyl-formamide / 6 h / 0 °C
2: trichlorophosphate / 19 h / 20 - 75 °C
3: sodium hydride / N,N-dimethyl-formamide / 15 h / 20 °C
4: palladium on activated charcoal; hydrogen / tetrahydrofuran; methanol; dichloromethane / 24 h / 20 °C
5: iron(II) ammonium sulfate; recombinant N-terminally His6-tagged Vitis vinifera cabernet sauvignon leucoanthocyanidin dioxygenase; α-ketoglutaric acid; sodium L-ascorbate; bovine catalase / 1 h / 30 °C / pH 6 / aq. phosphate buffer; Enzymatic reaction
With
iron(II) ammonium sulfate; α-ketoglutaric acid; palladium on activated charcoal; recombinant N-terminally His6-tagged Vitis vinifera cabernet sauvignon leucoanthocyanidin dioxygenase; hydrogen; sodium hydride; sodium L-ascorbate; bovine catalase; trichlorophosphate;
In
tetrahydrofuran; methanol; dichloromethane; N,N-dimethyl-formamide;
2: Vilsmeier-Haack reaction / 3: Horner-Wadsworth-Emmons olefination;
DOI:10.1002/cbic.201100044