[(C₂H₂(CCCCCC₆H₃(CH(CH₃)2)CCSi(CH(CH₃)2)3)2CCHOC₃H₆O)Fe(C₅H₅)]

Base Information

Chemical Name:[(C₂H₂(CCCCCC₆H₃(CH(CH₃)2)CCSi(CH(CH₃)2)3)2CCHOC₃H₆O)Fe(C₅H₅)]
CAS No.:569672-91-9
Molecular Formula:C₆₂H₇₆FeO₂Si₂
Molecular Weight:965.302
Hs Code.:

[(C<sub>2</sub>H<sub>2</sub>(CCCCCC<sub>6</sub>H<sub>3</sub>(CH(CH<sub>3</sub>)2)CCSi(CH(CH<sub>3</sub>)2)3)2CCHOC<sub>3</sub>H<sub>6</sub>O)Fe(C<sub>5</sub>H<sub>5</sub>)]

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Chemical Property of [(C₂H₂(CCCCCC₆H₃(CH(CH₃)2)CCSi(CH(CH₃)2)3)2CCHOC₃H₆O)Fe(C₅H₅)]

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Technology Process of [(C₂H₂(CCCCCC₆H₃(CH(CH₃)2)CCSi(CH(CH₃)2)3)2CCHOC₃H₆O)Fe(C₅H₅)]

There total 1 articles about [(C₂H₂(CCCCCC₆H₃(CH(CH₃)2)CCSi(CH(CH₃)2)3)2CCHOC₃H₆O)Fe(C₅H₅)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 46.0%

: 470484-18-5
[(C₂H₂(CCCH)2CCHOC₃H₆O)Fe(C₅H₅)]

: 478809-48-2
4-(bromoethynyl)-3-(triisopropylsilylethynyl)isopropylbenzene

: 569672-91-9
[(C₂H₂(CCCCCC₆H₃(CH(CH₃)2)CCSi(CH(CH₃)2)3)2CCHOC₃H₆O)Fe(C₅H₅)]

Guidance literature:: With bityllithium; CuI; propylamine; In tetrahydrofuran; (N2); Schlenk flask; soln. of BuLi was added dropwise to soln. of Fe complex in THF at -78°C; soln. was stirred for 30 min; warmed to 0°C; CuI was added; mixt. was stirred for 15 min; brought to -20°C; propylamine and alkyne added; successively; mixt. stirred at ambient temp. for 1 h; quenched with H2O;extd. (Et2O); org. layers dried (MgSO4); solvent removed (vac.); chromd . (SiO2, hexane/CH2Cl2, 9/1);
DOI:10.1016/S0022-328X(03)00145-1

Reference yield: 58.0%

: 569672-91-9
[(C₂H₂(CCCCCC₆H₃(CH(CH₃)2)CCSi(CH(CH₃)2)3)2CCHOC₃H₆O)Fe(C₅H₅)]

: 18107-18-1
diazomethyl-trimethyl-silane

: 569672-92-0
[(C₂H₂(CCCCCC₆H₃(CH(CH₃)2)CCSi(CH(CH₃)2)3)2CCCH)Fe(C₅H₅)]

Guidance literature:: With para-toluenesulfonic acid; BuLi; In tetrahydrofuran; water; soln. of Fe complex, acid in THF/H2O stirred for 1 h under exclusion of light; quenched (H2O); extd. (Et2O); solvent removed (vac.); dried (vac.); soln. of BuLi added dropwise to soln. of Me3SiC(N2)H/THF in Schlenk flask at -78°C; stirred for 5; min; warmed to 0°C; soln. homogenized; cooled to -50°C; THF added to flask with Fe residue (N2); soln. added to soln. of Li compd.at temp. below -40°C; stirred for 15 min; aq. NH4Cl added; warme d to room temp.; extd. (Et2O); chromd;
DOI:10.1016/S0022-328X(03)00145-1