CpFe(CO)2SeCOC₆H₃(COCl)2

Base Information

Chemical Name:CpFe(CO)2SeCOC₆H₃(COCl)2
CAS No.:1384426-18-9
Molecular Formula:C₁₆H₈Cl₂FeO₅Se
Molecular Weight:485.95
Hs Code.:

CpFe(CO)2SeCOC<sub>6</sub>H<sub>3</sub>(COCl)2

Synonyms:

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Chemical Property of CpFe(CO)2SeCOC₆H₃(COCl)2

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Technology Process of CpFe(CO)2SeCOC₆H₃(COCl)2

There total 2 articles about CpFe(CO)2SeCOC₆H₃(COCl)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

: ((η5-C5H5)Fe(CO)2)2Se

: 4422-95-1
1,3,5-benzene tris(carbonyl chloride)

: 1384426-18-9
CpFe(CO)2SeCOC₆H₃(COCl)2

Guidance literature:: In diethyl ether; byproducts: CpFe(CO)2Cl; under N2, Schlenk or vac. line technique; Et2O soln. of Fe complex addeddropwise at room temp. to 1,3,5-C6H3(COCl)3 in Et2O; stirred for 3 h at room temp.; volatiles removed in vac., residue redissolved in CH2Cl2, transferred into silica gel column; eluted with CH2Cl2/hexane (6:4 vol.); elem. anal.;
DOI:10.1002/zaac.201100541

Reference yield: 23.0%

: ((η5-C5H5)Fe(CO)2)2Se

: 4422-95-1
1,3,5-benzene tris(carbonyl chloride)

: 1384426-18-9
CpFe(CO)2SeCOC₆H₃(COCl)2

: 1384426-24-7
[CpFe(CO)2SeCO]2C₆H₃COCl

Guidance literature:: In diethyl ether; under N2, Schlenk or vac. line technique; to Et2O soln. of Fe complex added dropwise at room temp. 1,3,5-C6H3(COCl)3 in Et2O; stirred for 4 h atroom temp.; volatiles removed in vac., residue redissolved in CH2Cl2, transferred into silica gel column; eluted with CH2Cl2/hexane (9:1 vol.); second band recrystd. from CH2Cl2/hexaneelem. anal.;
DOI:10.1002/zaac.201100541

Reference yield: 73.0%

: 1384426-18-9
CpFe(CO)2SeCOC₆H₃(COCl)2

: 108-98-5
thiophenol

: 1384426-20-3
CpFe(CO)2SeCOC₆H₃(COS(Ph))2

Guidance literature:: With pyridine; In tetrahydrofuran; under N2, Schlenk or vac. line technique; THF soln. of PhSH and Fe complex in presence of few drops of pyridine heated to reflux for 4 h; volatiles removed under vac., residue redissolved in CH2Cl2, introduced to silica gel column; eluted with THF/hexane, collected, dried, recrystd. from CH2Cl2/hexane; elem. anal.;
DOI:10.1002/zaac.201100541