diaquatris(1-phenyl-4,4,4-trifluorobutane-1,3-dionato)europium(III)

Base Information

• Chemical Name: diaquatris(1-phenyl-4,4,4-trifluorobutane-1,3-dionato)europium(III)
• CAS No.: 25473-11-4
• Molecular Formula: C₃₀H₂₂EuF₉O₈
• Molecular Weight: 833.446
• Mol file: 25473-11-4.mol

Synonyms:

Chemical Property of diaquatris(1-phenyl-4,4,4-trifluorobutane-1,3-dionato)europium(III)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of diaquatris(1-phenyl-4,4,4-trifluorobutane-1,3-dionato)europium(III)

There total 4 articles about diaquatris(1-phenyl-4,4,4-trifluorobutane-1,3-dionato)europium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

1-Phenyl-4,4,4-trifluorobutane-1,3-dione (326-06-7) + europium(III) chloride hexahydrate + water (7732-18-5) → diaquatris(1-phenyl-4,4,4-trifluorobutane-1,3-dionato)europium(III) (25473-11-4,153246-07-2)

Guidance literature:

With ammonia; In methanol; at 20 ℃; for 4h; pH=Ca. 7;

DOI:10.1246/bcsj.20170254

Reference yield:

europium(III) perchlorate + 1-Phenyl-4,4,4-trifluorobutane-1,3-dione (326-06-7) → diaquatris(1-phenyl-4,4,4-trifluorobutane-1,3-dionato)europium(III) (25473-11-4,153246-07-2)

Guidance literature:

With sodium hydroxide; In ethanol; water; pH 6-7, reflux (4 h); filtration, recrystn. (EtOH), drying (80°C, over P2O5, reduced pressure);

DOI:10.1039/CC9960001199

Reference yield:

europium(III) chloride hexahydrate + 1-Phenyl-4,4,4-trifluorobutane-1,3-dione (326-06-7) + water (7732-18-5) → diaquatris(1-phenyl-4,4,4-trifluorobutane-1,3-dionato)europium(III) (25473-11-4,153246-07-2)

Guidance literature:

With KO-tBu; In water; diketone (1 3 mmol) added to aq. soln. of KO-tBu (3 mmol), stirred for 10 min, aq. soln. of Eu compd. (1 mmol) added, stirred under N2 for 30 min at 60°C and at room temp. for 3 h; ppt. filtered off, washed (cold water, hexane), dried (vac.), recrystd. (acetone/ethanol=1/1);

DOI:10.1016/j.ica.2007.04.049

upstream raw materials:

1-Phenyl-4,4,4-trifluorobutane-1,3-dione

water

Downstream raw materials:

(1,10-phenanthroline-N-oxide)tris(1-phenyl-4,4,4-trifluorobutane-1,3-dionato)europium(III)