{9,9-(PPh₃)2-arachno-6,9-SPtB₈H₁₀

Base Information

• Chemical Name: {9,9-(PPh₃)2-arachno-6,9-SPtB₈H₁₀
• CAS No.: 64560-46-9
• Molecular Formula: C₃₆H₄₀B₈P₂PtS
• Molecular Weight: 848.295
• Mol file: 64560-46-9.mol

Synonyms:

Chemical Property of {9,9-(PPh₃)2-arachno-6,9-SPtB₈H₁₀

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {9,9-(PPh₃)2-arachno-6,9-SPtB₈H₁₀

There total 3 articles about {9,9-(PPh₃)2-arachno-6,9-SPtB₈H₁₀ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

tetrakis(triphenylphosphine)platinum (14221-02-4) + arachno-4-SB8H12 (73711-47-4) → {9,9-(PPh3)2-arachno-6,9-SPtB8H10 (64560-46-9)

Guidance literature:

In benzene; byproducts: H2; to B-compound dissolved in benzene Pt(PPh3)4 was added, when initial exothermic reaction had ceased, mixt. refluxed for additional 30 min; crystn. on standing overnight at room temp., crystals filtered in vacuo, washed with cold benzene, recrystd. from methylenchloride-hexane; elem. anal.;

Reference yield: 95.0%

tetrakis(triphenylphosphine)platinum (14221-02-4) + cesium(1+)*arachno-6-SB9H12(1-) → {9,9-(PPh3)2-arachno-6,9-SPtB8H10 (64560-46-9)

Guidance literature:

DOI:10.1016/S0277-5387(00)80509-4

Reference yield:

tetrakis(triphenylphosphine)platinum (14221-02-4) + arachno-4-SB8H12 → {9,9-(PPh3)2-arachno-6,9-SPtB8H10 (64560-46-9)

Guidance literature:

In benzene; (dry N2); by the method of B. Stibr, K. Base, S. Hermanek, and I. Plesik, Chem. Comm., No. 4, 150 (1976); pptd. from soln.;

upstream raw materials:

tetrakis(triphenylphosphine)platinum

arachno-4-SB₈H₁₂