bis[1,4-bis(3,5-dimethylphenyl)tetraazabutadiene]nickel

Base Information

Chemical Name:bis[1,4-bis(3,5-dimethylphenyl)tetraazabutadiene]nickel
CAS No.:73440-07-0
Molecular Formula:C₃₂H₃₆N₈Ni
Molecular Weight:591.381
Hs Code.:

Synonyms:

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Chemical Property of bis[1,4-bis(3,5-dimethylphenyl)tetraazabutadiene]nickel

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Technology Process of bis[1,4-bis(3,5-dimethylphenyl)tetraazabutadiene]nickel

There total 2 articles about bis[1,4-bis(3,5-dimethylphenyl)tetraazabutadiene]nickel which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 25.0%

: 1295-35-8
bis(1,5-cyclooctadiene)nickel ⁽⁰⁾

: 70334-59-7
1-azido-3,5-dimethylbenzene

: 73440-07-0
bis[1,4-bis(3,5-dimethylphenyl)tetraazabutadiene]nickel

Guidance literature:: In toluene; byproducts: N2; azide was added to a soln. of complex at -10°C, exothermic reaction with N2 evolution; Soxhlet extn. (toluene), concn. in vac., chromy. (silica-60, toluene), washing with pentane; elem. anal.;
DOI:10.1021/ic00136a051

Reference yield:

: 73440-09-2
[1,4-bis(4-tolyl)tetraazabutadiene](η5-cyclopentadienyl)nickel

: 70334-59-7
1-azido-3,5-dimethylbenzene

: 73432-46-9
bis[1,4-bis(4-tolyl)tetraazabutadiene]nickel

: 73440-07-0
bis[1,4-bis(3,5-dimethylphenyl)tetraazabutadiene]nickel

: 83475-76-7
[Ni((C₆H₄Me-4)2N₄)((C₆H₃Me₂-3,5)2N₄)]

: [Ni((C₆H₄Me-4)N₄(C₆H₃Me₂-3,5))2]

: 83678-62-0
[Ni((C₆H₃Me₂-3,5)2N₄)((C₆H₃Me₂-3,5)N₄(C₆H₄Me-4))]

Guidance literature:: In toluene; under N2, Ni-complex refluxed with azide (molar ratio 1:47.8) in toluene for 45 min; further products; concd. in vac., chromd. in air (silica column, toluene, THF-toluene), concd. to dryness; analyzed by field desorption mass spectra;

Reference yield: 80.0%

: 1295-35-8
bis(1,5-cyclooctadiene)nickel ⁽⁰⁾

: 73440-07-0
bis[1,4-bis(3,5-dimethylphenyl)tetraazabutadiene]nickel

: 119072-55-8,7188-38-7
tert-butylisonitrile

: 78677-38-0
bis(tert-butyl isocyanide)[1,4-bis(3,5-dimethylphenyl)tetraazabutadiene]nickel

Guidance literature:: In toluene; a soln. of complex was added to a slurry of Ni(COD)2 and excess of t-BuNC in toluene, heated at 60°C for 16 h; addition of pentane at room temp., cooling at -20°C for 8 h; elem. anal.;
DOI:10.1021/ic00136a051