C₃₈H₅₂O₁₃Si

Base Information

• Chemical Name: C₃₈H₅₂O₁₃Si
• CAS No.: 675584-84-6
• Molecular Formula: C₃₈H₅₂O₁₃Si
• Molecular Weight: 744.909
• Mol file: 675584-84-6.mol

Synonyms:

Chemical Property of C₃₈H₅₂O₁₃Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₈H₅₂O₁₃Si

There total 1 articles about C₃₈H₅₂O₁₃Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-debenzoyl-7-(triethylsilyl)-2-(m-methoxybenzoyl)-13-oxobaccatin III (189190-95-2) → C38H52O13Si (675584-84-6)

Guidance literature:

2-debenzoyl-7-(triethylsilyl)-2-(m-methoxybenzoyl)-13-oxobaccatin III; With 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; potassium tert-butylate; In tetrahydrofuran; at -65 ℃; for 0.25h;

With 3-(3-nitrophenyl)-2-(phenylsulfonyl)-1,2-oxaziridine; In tetrahydrofuran; at -65 - -55 ℃; for 1h;

DOI:10.1016/j.bmcl.2005.08.066

Reference yield:

C38H52O13Si (675584-84-6) + 1,1'-carbonyldiimidazole (530-62-1) → C39H50O14Si (675584-85-7)

Guidance literature:

With 1H-imidazole; In dichloromethane; at 40 ℃; for 1.5h;

DOI:10.1016/j.bmcl.2005.08.066

Reference yield:

C38H52O13Si (675584-84-6) → C39H52O14Si

Guidance literature:

Multi-step reaction with 2 steps

1: 230 mg / imidazole / CH₂Cl₂ / 1.5 h / 40 °C

2: 19 percent / Et₄N(BH₄) / methanol / 2.5 h / -40 - 0 °C

With 1H-imidazole; tetraethylammonium borohydride; In methanol; dichloromethane;

DOI:10.1016/j.bmcl.2005.08.066

upstream raw materials:

2-debenzoyl-7-(triethylsilyl)-2-(m-methoxybenzoyl)-13-oxobaccatin III

Downstream raw materials:

C₃₉H₅₀O₁₄Si

C₃₉H₅₂O₁₄Si

C₄₅H₅₉NO₁₈

C₅₁H₇₃NO₁₈Si