(1R,2S,3R,4R,5S,6S)-3,4-Bis-benzyloxy-2,6-bis-benzyloxymethoxy-5-(4-methoxy-benzyloxy)-cyclohexanol

Base Information

Chemical Name:(1R,2S,3R,4R,5S,6S)-3,4-Bis-benzyloxy-2,6-bis-benzyloxymethoxy-5-(4-methoxy-benzyloxy)-cyclohexanol
CAS No.:209050-73-7
Molecular Formula:C₄₄H₄₈O₉
Molecular Weight:720.86
Hs Code.:

Synonyms:

Suppliers and Price of (1R,2S,3R,4R,5S,6S)-3,4-Bis-benzyloxy-2,6-bis-benzyloxymethoxy-5-(4-methoxy-benzyloxy)-cyclohexanol

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Chemical Property of (1R,2S,3R,4R,5S,6S)-3,4-Bis-benzyloxy-2,6-bis-benzyloxymethoxy-5-(4-methoxy-benzyloxy)-cyclohexanol

Chemical Property:

Purity/Quality:

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Hazard Codes:

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Technology Process of (1R,2S,3R,4R,5S,6S)-3,4-Bis-benzyloxy-2,6-bis-benzyloxymethoxy-5-(4-methoxy-benzyloxy)-cyclohexanol

There total 10 articles about (1R,2S,3R,4R,5S,6S)-3,4-Bis-benzyloxy-2,6-bis-benzyloxymethoxy-5-(4-methoxy-benzyloxy)-cyclohexanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: Acetic acid (1R,2R,3R,4R,5S,6R)-3,4-bis-benzyloxy-2,6-bis-benzyloxymethoxy-5-(4-methoxy-benzyloxy)-cyclohexyl ester

: 209050-73-7
(1R,2S,3R,4R,5S,6S)-3,4-Bis-benzyloxy-2,6-bis-benzyloxymethoxy-5-(4-methoxy-benzyloxy)-cyclohexanol

Guidance literature:: With sodium hydroxide; In tetrahydrofuran; water; for 16h; Ambient temperature;
DOI:10.1016/S0040-4039(98)00737-0

Reference yield:

: 18929-63-0
methyl 4,6-O-para-methoxybenzylidene-α-D-glucopyranoside

: 209050-73-7
(1R,2S,3R,4R,5S,6S)-3,4-Bis-benzyloxy-2,6-bis-benzyloxymethoxy-5-(4-methoxy-benzyloxy)-cyclohexanol

Guidance literature:: Multi-step reaction with 8 steps

1: NaH / dimethylformamide / 5 h / Ambient temperature

2: 95 percent / lithium aluminum hydride, aluminum chloride / diethyl ether; CH₂Cl₂ / 3 h / 0 °C

3: 1.) (COCl)2, DMSO; 2.) Et₃N / CH₂Cl₂ / 0.5 h / -78 °C

4: K₂CO₃ / acetonitrile / 20 h / Ambient temperature

5: 75 percent / mercuric acetate, aq. NaCl / acetone / 20 h / Ambient temperature

6: 63 percent / sodium triacetoxy borohydride / acetic acid; acetonitrile / 1 h / Ambient temperature

7: H⁽¹⁺⁾Sponge, Bu₄NI / acetonitrile / 48 h / 40 °C

8: NaOH / tetrahydrofuran; H₂O / 16 h / Ambient temperature

With sodium hydroxide; lithium aluminium tetrahydride; aluminium trichloride; oxalyl dichloride; mercury(II) diacetate; hydrogen cation; tetra-(n-butyl)ammonium iodide; sodium tris(acetoxy)borohydride; sodium hydride; potassium carbonate; dimethyl sulfoxide; triethylamine; sodium chloride; In tetrahydrofuran; diethyl ether; dichloromethane; water; acetic acid; N,N-dimethyl-formamide; acetone; acetonitrile;
DOI:10.1016/S0040-4039(98)00737-0

Reference yield:

: 2186-92-7
p-Anisaldehyde dimethyl acetal

: 209050-73-7
(1R,2S,3R,4R,5S,6S)-3,4-Bis-benzyloxy-2,6-bis-benzyloxymethoxy-5-(4-methoxy-benzyloxy)-cyclohexanol

Guidance literature:: Multi-step reaction with 9 steps

1: p-toluenesulfonic acid / dimethylformamide / 6 h / 65 °C

2: NaH / dimethylformamide / 5 h / Ambient temperature

3: 95 percent / lithium aluminum hydride, aluminum chloride / diethyl ether; CH₂Cl₂ / 3 h / 0 °C

4: 1.) (COCl)2, DMSO; 2.) Et₃N / CH₂Cl₂ / 0.5 h / -78 °C

5: K₂CO₃ / acetonitrile / 20 h / Ambient temperature

6: 75 percent / mercuric acetate, aq. NaCl / acetone / 20 h / Ambient temperature

7: 63 percent / sodium triacetoxy borohydride / acetic acid; acetonitrile / 1 h / Ambient temperature

8: H⁽¹⁺⁾Sponge, Bu₄NI / acetonitrile / 48 h / 40 °C

9: NaOH / tetrahydrofuran; H₂O / 16 h / Ambient temperature

With sodium hydroxide; lithium aluminium tetrahydride; aluminium trichloride; oxalyl dichloride; mercury(II) diacetate; hydrogen cation; tetra-(n-butyl)ammonium iodide; sodium tris(acetoxy)borohydride; sodium hydride; potassium carbonate; toluene-4-sulfonic acid; dimethyl sulfoxide; triethylamine; sodium chloride; In tetrahydrofuran; diethyl ether; dichloromethane; water; acetic acid; N,N-dimethyl-formamide; acetone; acetonitrile;
DOI:10.1016/S0040-4039(98)00737-0