cis-[Pt(C₆H₄Me-4)(Ph₂PCH₂PPh₂)]

Base Information

• Chemical Name: cis-[Pt(C₆H₄Me-4)(Ph₂PCH₂PPh₂)]
• CAS No.: 58006-03-4
• Molecular Formula: C₃₉H₃₆P₂Pt
• Molecular Weight: 761.742
• Mol file: 58006-03-4.mol

Synonyms:

Chemical Property of cis-[Pt(C₆H₄Me-4)(Ph₂PCH₂PPh₂)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-[Pt(C₆H₄Me-4)(Ph₂PCH₂PPh₂)]

There total 3 articles about cis-[Pt(C₆H₄Me-4)(Ph₂PCH₂PPh₂)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

trans-Pt(4-MeC6H4)2(SMe2)2 + bis-diphenylphosphinomethane (2071-20-7) → cis-[Pt(C6H4Me-4)(Ph2PCH2PPh2)] (58006-03-4)

Guidance literature:

In diethyl ether; a soln. of dppm was added to a soln. of complex, N2 atm.; filtration, washing a ppt. with ether; elem. anal.;

DOI:10.1016/S0022-328X(00)84806-8

Reference yield: 63.0%

dichloro(bis(diphenylphosphino)methane)platinum(II) (52595-94-5) + para-bromotoluene (106-38-7) → cis-[Pt(C6H4Me-4)(Ph2PCH2PPh2)] (58006-03-4)

Guidance literature:

With magnesium; In tetrahydrofuran; benzene; to the soln. of Grignard reagent prepared from Mg and the appropriate bromide in THF under N2 the Pt complex and benzene were added, the mixt. was heated under reflux for 1 h; the mixt. was cooled, methanol was added, the solvents were removed in vacuo, extn. with CH2Cl2, crystn. from CH2Cl2-ethanol, elem. anal.;

DOI:10.1039/DT9850001501

Reference yield:

cis,cis-[(p-CH3C6H4)2Pt(μ-S(CH3)2)(μ-(((C6H5)2P)2CH2)Pt(p-CH3C6H4)2)] (287376-86-7) + bis-diphenylphosphinomethane (2071-20-7) → cis-[Pt(C6H4Me-4)(Ph2PCH2PPh2)] (58006-03-4)

Guidance literature:

In not given;

DOI:10.1021/om990784t

upstream raw materials:

bis-diphenylphosphinomethane

dichloro(bis(diphenylphosphino)methane)platinum(II)

para-bromotoluene

cis,cis-[(p-CH3C6H4)2Pt(μ-S(CH3)2)(μ-(((C6H5)2P)2CH2)Pt(p-CH3C6H4)2)]

Downstream raw materials:

cis,cis-[Me2Pt(μ-SMe2)(μ-dppm)Pt(p-tolyl)2]

Pt((C₆H₅)2PCH₂P(C₆H₅)2)2(C₆H₄(CH₃))2

Pt((C₆H₅)2PCH₂P(C₆H₅)2)(C₆H₄(CH₃))2(CH₃)I