(η6-[O-benzyl-N-(α-methylbenzyl)hydroxyamino]benzene)chromium tricarbonyl

Base Information

• Chemical Name: (η6-[O-benzyl-N-(α-methylbenzyl)hydroxyamino]benzene)chromium tricarbonyl
• CAS No.: 395663-86-2
• Molecular Formula: C₂₄H₂₁CrNO₄
• Molecular Weight: 439.431
• Mol file: 395663-86-2.mol

Synonyms:

Chemical Property of (η6-[O-benzyl-N-(α-methylbenzyl)hydroxyamino]benzene)chromium tricarbonyl

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of (η6-[O-benzyl-N-(α-methylbenzyl)hydroxyamino]benzene)chromium tricarbonyl

There total 1 articles about (η6-[O-benzyl-N-(α-methylbenzyl)hydroxyamino]benzene)chromium tricarbonyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

(η6-fluorobenzene)tricarbonylchromium (12082-05-2) + O-benzyl-N-(1-phenylethyl)hydroxylamine (120254-57-1) → (η6-[O-benzyl-N-(α-methylbenzyl)hydroxyamino]benzene)chromium tricarbonyl (395663-86-2)

Guidance literature:

With BuLi; In tetrahydrofuran; hexane; BuLi in hexane was added dropwise to soln. hydroxylamine in THF at -78°C and stirred for 30 min at -78°C, react. mixt. was warmed to 0°C, (C6H5F)Cr(CO)3 in THF was added at 0°C, react. mixt. was stirred overnight at r.t.; react. was quenched with MeOH, solvent was removed under reduced pressure, residue was dissolved in EtOAc, filtered through MgSO4 and evapd. in vacuo, column chromy. followed by recrystn. from petroleum ether/ether; elem. anal.;

upstream raw materials:

(η6-fluorobenzene)tricarbonylchromium

O-benzyl-N-(1-phenylethyl)hydroxylamine