[RuCl(CO)(P(C₆H₅)3)2(CHCHCH(OC₂H₅)2)]

Base Information

• Chemical Name: [RuCl(CO)(P(C₆H₅)3)2(CHCHCH(OC₂H₅)2)]
• CAS No.: 638210-34-1
• Molecular Formula: C₄₄H₄₃ClO₃P₂Ru
• Molecular Weight: 818.294
• Mol file: 638210-34-1.mol

Synonyms:

Chemical Property of [RuCl(CO)(P(C₆H₅)3)2(CHCHCH(OC₂H₅)2)]

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of [RuCl(CO)(P(C₆H₅)3)2(CHCHCH(OC₂H₅)2)]

There total 1 articles about [RuCl(CO)(P(C₆H₅)3)2(CHCHCH(OC₂H₅)2)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

(carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II) (157072-60-1,61521-25-3,166941-05-5,16971-33-8) + Propiolaldehyde diethyl acetal (10160-87-9) → [RuCl(CO)(P(C6H5)3)2(CHCHCH(OC2H5)2)] (638210-34-1)

Guidance literature:

In dichloromethane; under N2; alkyne slowly added to suspn. of Ru complex in CH2Cl2, stirredat room temp. for 5 min; concd. under vac., n-hexane added, ppt. filtered off, washed with n-hexane, dried under vac.; elem. anal.;

DOI:10.1016/S0022-328X(03)00704-6

Reference yield: 32.0%

[RuCl(CO)(P(C6H5)3)2(CHCHCH(OC2H5)2)] (638210-34-1) + potassium tris(1-pyrazolyl)borate → [Ru(hydridotris(pyrazolyl)borate)(CO)(CHCHCHO)(PPh3)]

Guidance literature:

In dichloromethane; under N2; mixt. of Ru complex and K salt in CH2Cl2 stirred at room temp.for 2 h, diethyl ether added, mixt. stirred for 30 min; filtered through Celite, column chromy. (silica gel, under N2, hexane, CH2Cl2, and methanol), methanol fraction collected and concd., solid sepd. and dried under vac.; elem. anal.;

DOI:10.1016/S0022-328X(03)00704-6

upstream raw materials:

(carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II)

Propiolaldehyde diethyl acetal