[(η5-C5Me5)Ru(P(i)Pr3)(mesitylborane)]B(C6F5)4

Base Information

• Chemical Name: [(η5-C5Me5)Ru(P(i)Pr3)(mesitylborane)]B(C6F5)4
• CAS No.: 1052726-47-2
• Molecular Formula: C₂₄BF₂₀*C₂₈H₄₉BPRu
• Molecular Weight: 1207.59
• Mol file: 1052726-47-2.mol

Synonyms:

Chemical Property of [(η5-C5Me5)Ru(P(i)Pr3)(mesitylborane)]B(C6F5)4

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of [(η5-C5Me5)Ru(P(i)Pr3)(mesitylborane)]B(C6F5)4

There total 2 articles about [(η5-C5Me5)Ru(P(i)Pr3)(mesitylborane)]B(C6F5)4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

lithium tetrakis(pentafluorophenyl)borate ethyl etherate + (η5-C5Me5)Ru(P(i)Pr3)(BH2(2,4,6-trimethylphenyl)Cl) (1052726-44-9) → [(η5-C5Me5)Ru(P(i)Pr3)(mesitylborane)]B(C6F5)4 (1052726-47-2)

Guidance literature:

In fluorobenzene; hexane; soln. of RuB-complex in hexane treated with LiB-compound in fluorobenzene; monitored by NMR;

DOI:10.1021/ic801300m

Reference yield: 54.0%

lithium(etherate)2.5 tetrakis(pentafluorophenyl)borate + (η5-C5Me5)Ru(P(i-Pr)3)Cl + mesitylborane (45741-00-2) → [(η5-C5Me5)Ru(P(i)Pr3)(mesitylborane)]B(C6F5)4 (1052726-47-2)

Guidance literature:

In fluorobenzene; hexane; (N2); a soln. of Ru complex in hexanes treated with BH2C6H2(CH3)3, stirred at ambient temp. for 0.25 h, a C6H5F soln. of Li salt added, stirred for 0.75 h; filtered, evapd. (vac.), triturated with pentane, dried in vac., recrystd. (Et2O); elem. anal.;

DOI:10.1021/ic1022328

Reference yield:

[(η5-C5Me5)Ru(P(i)Pr3)(mesitylborane)]B(C6F5)4 (1052726-47-2) → (i-Pr)3P*BH2Mes (1052726-50-7)

Guidance literature:

With CH₂CHC(CH₃)3; In not given; (N2); heating at 50°C for hours; not isolated, detected by NMR;

DOI:10.1021/ic1022328

upstream raw materials:

(η5-C5Me5)Ru(P(i)Pr3)(BH2(2,4,6-trimethylphenyl)Cl)

mesitylborane

Downstream raw materials:

(i-Pr)3P*BH₂Mes