diethylphenylphosphonium trans-tetrachlorobis(diethylphenylphosphine)iridate(III)

Base Information

• Chemical Name: diethylphenylphosphonium trans-tetrachlorobis(diethylphenylphosphine)iridate(III)
• CAS No.: 26998-36-7
• Molecular Formula: C₁₀H₁₅P*C₂₀H₃₀Cl₄IrP₂*H
• Molecular Weight: 833.649
• Mol file: 26998-36-7.mol

Synonyms:

Chemical Property of diethylphenylphosphonium trans-tetrachlorobis(diethylphenylphosphine)iridate(III)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of diethylphenylphosphonium trans-tetrachlorobis(diethylphenylphosphine)iridate(III)

There total 1 articles about diethylphenylphosphonium trans-tetrachlorobis(diethylphenylphosphine)iridate(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

iridium trichloride hydrate + diethyl-phenyl-phosphine (1605-53-4) → diethylphenylphosphonium trans-tetrachlorobis(diethylphenylphosphine)iridate(III) (26998-36-7)

Guidance literature:

With HCl; In hydrogenchloride; ethanol; soln. of PEt2Ph and IrCl3*nH2O in a deoxygenated mixt. of concd. HCl and EtOH was refluxed for 5 h; evapd., residue was washed with boiling toluene, recrystd. from ethanol;

DOI:10.1039/DT9870001901

Reference yield:

diethylphenylphosphonium trans-tetrachlorobis(diethylphenylphosphine)iridate(III) (26998-36-7) → trans-tetrachlorobis(diethylphenylphosphine)iridium(IV) (22371-12-6)

Guidance literature:

With chlorine; In chloroform; Cl2 was bubbled through a soln. of Ir(III)-complex in CHCl3; yield 10% based on IrCl3*nH2O; evapd., residue was recrystd. from CH2Cl2-light petroleum; elem. anal.;

DOI:10.1039/DT9870001901

upstream raw materials:

diethyl-phenyl-phosphine

Downstream raw materials:

trans-tetrachlorobis(diethylphenylphosphine)iridium(IV)