[(η2-1,2-bis(diphenylphosphino)ethane)(η5-C5Me5)Fe-C2-ant-Br]

Base Information

Chemical Name:[(η2-1,2-bis(diphenylphosphino)ethane)(η5-C5Me5)Fe-C2-ant-Br]
CAS No.:1020211-29-3
Molecular Formula:C₅₂H₄₇BrFeP₂
Molecular Weight:869.644
Hs Code.:

Synonyms:

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Chemical Property of [(η2-1,2-bis(diphenylphosphino)ethane)(η5-C5Me5)Fe-C2-ant-Br]

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Technology Process of [(η2-1,2-bis(diphenylphosphino)ethane)(η5-C5Me5)Fe-C2-ant-Br]

There total 2 articles about [(η2-1,2-bis(diphenylphosphino)ethane)(η5-C5Me5)Fe-C2-ant-Br] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: (η(2)-1,2-bis(diphenylphosphino)ethane)(η(5)-pentamethylcyclopentadienyl)Fe-C.tplbond.CH

: 523-27-3
9,10-Dibromoanthracene

: 1020211-29-3
[(η2-1,2-bis(diphenylphosphino)ethane)(η5-C5Me5)Fe-C2-ant-Br]

Guidance literature:: With catalyst:[PtCl₂(P(C₆H₅)3)4]/CuCl; In further solvent(s); (Ar, Schlenk) a mixt. of Fe-complex, anthracene-compound, Pd-complex, CuI and diisopropylamine was stirred at 50°C for 2 days; evapd. to dryness, dissolved in ether, passed through a short pad of celite under Ar, the solvent was removed;
DOI:10.1021/om701278e

Reference yield:

: 313698-93-0
9-bromo-10-(trimethylsilylethynyl)anthracene

: (1,2,3,4,5-pentamethylcyclopentadienyl)(1,2-bis(diphenylphosphino)ethane)iron(II)Cl

: 1020211-29-3
[(η2-1,2-bis(diphenylphosphino)ethane)(η5-C5Me5)Fe-C2-ant-Br]

Guidance literature:: With potassium carbonate; NaB(C₆H₅)4; potassium tert-butoxide; In methanol; byproducts: KCl; (Ar, Schlenk) anthracene-compound in methanol was stirred for 6 h in thepresence of K2CO3, Fe-complex and NaB(C6H5)4 were added, stirred for 16 h, KOC(CH3)3 was added, stirred for 4 h; the solvent was removed, the residue was dissolved in ether, passed through a short pad of celite under Ar, evapd. to dryness;
DOI:10.1021/om701278e

Reference yield: 45.0%

: ferrocenium hexafluorophosphate

: 1020211-29-3
[(η2-1,2-bis(diphenylphosphino)ethane)(η5-C5Me5)Fe-C2-ant-Br]

: 1020211-37-3
[(η2-1,2-bis(diphenylphosphino)ethane)(η5-C5Me5)Fe-C2-ant-Br][PF6]

Guidance literature:: In tetrahydrofuran; (Ar, Schlenk) complexes in THF were stirred at 3 h at -80°C; evapd., the residue was dissolved in CH2Cl2, pptd. by addn. of diethyl ether twice, the solid was dried under vac.;
DOI:10.1021/om701278e