[(η5-methylcyclopentadienyl)3Mo3S4][p-toluenesulfonate]

Base Information

• Chemical Name: [(η5-methylcyclopentadienyl)3Mo3S4][p-toluenesulfonate]
• CAS No.: 351420-47-8
• Molecular Formula: C₇H₇O₃S*C₁₈H₂₁Mo₃S₄
• Molecular Weight: 824.646
• Mol file: 351420-47-8.mol

Synonyms:

Chemical Property of [(η5-methylcyclopentadienyl)3Mo3S4][p-toluenesulfonate]

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of [(η5-methylcyclopentadienyl)3Mo3S4][p-toluenesulfonate]

There total 1 articles about [(η5-methylcyclopentadienyl)3Mo3S4][p-toluenesulfonate] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

[(H2O)9Mo3S4][p-toluenesulfonate]4*9H2O + methylcyclopentadienylthallium(I) → [(η5-methylcyclopentadienyl)3Mo3S4][p-toluenesulfonate] (360559-86-0,351420-47-8)

Guidance literature:

With p-toluenesulfonic acid; In tetrahydrofuran; pyridine; under N2 atm. ((H2O)9Mo3S4)(pts)4*9H2O and Hpts in triethylorthoformate were stirred at room temp. for 16 h, soln. was concd., residue was washed with Et2O, dissolved in MeCN, stirred for 1 h, evapd., redissolved in THF, TlCp' in CH2Cl2 was added, 3 h; soln. was filtered and evapd., residue was purified by column chromy. onsilica (CH2Cl2/MeOH); elem. anal.;

DOI:10.1021/om010151q

Reference yield: 93.0%

[(η5-methylcyclopentadienyl)3Mo3S4][p-toluenesulfonate] (360559-86-0,351420-47-8) + copper(l) chloride → [(η5-methylcyclopentadienyl)3Mo3S4Cu(Cl)][p-toluenesulfonate]

Guidance literature:

In dichloromethane; under N2 atm. to soln. ((η5-Cp')3Mo3S4)(pts) in CH2Cl2 CuCl was added and stirred for 2 h; react. mixt. was filtered, evapd. to dryness in vacuo, residue was recrystd. from THF, MeOH, and pentane, ppt. was filtered, washed with pentaneand dried in vacuo; elem. anal.;

DOI:10.1016/S0020-1693(03)00497-3

Reference yield: 89.0%

bis(1,5-cyclooctadiene)nickel (0) (1295-35-8) + [(η5-methylcyclopentadienyl)3Mo3S4][p-toluenesulfonate] (360559-86-0,351420-47-8) + triphenylphosphine (603-35-0) → [(η5-methylcyclopentadienyl)3Mo3S4Ni(PPh3)][p-toluenesulfonate]

Guidance literature:

In tetrahydrofuran; under N2 atm. suspn. (Ni(cod)2) in THF was added to suspn. ((η5-Cp')3Mo3S4)(pts) in THF and stirred for 30 min, PPh3 was added and stirred for 2 h; ppt. was filtered and recrystd. from CH2Cl2/pentane; elem. anal.;

DOI:10.1021/om010151q