Cu(1,8-bis(4-[2,2':6',2'']terpyridin-4'-yl-benzyl)-1,4,8,11-tetraazacyclotetradecan-5,12-dione)

Base Information

• Chemical Name: Cu(1,8-bis(4-[2,2':6',2'']terpyridin-4'-yl-benzyl)-1,4,8,11-tetraazacyclotetradecan-5,12-dione)
• CAS No.: 1013931-05-9
• Molecular Formula: C₅₄H₄₈CuN₁₀O₂
• Molecular Weight: 932.587
• Mol file: 1013931-05-9.mol

Synonyms:

Chemical Property of Cu(1,8-bis(4-[2,2':6',2'']terpyridin-4'-yl-benzyl)-1,4,8,11-tetraazacyclotetradecan-5,12-dione)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Cu(1,8-bis(4-[2,2':6',2'']terpyridin-4'-yl-benzyl)-1,4,8,11-tetraazacyclotetradecan-5,12-dione)

There total 1 articles about Cu(1,8-bis(4-[2,2':6',2'']terpyridin-4'-yl-benzyl)-1,4,8,11-tetraazacyclotetradecan-5,12-dione) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 32.0%

1,8-bis-(4-[2,2';6',2'']terpyridin-4'-yl-benzyl)-1,4,8,11-tetraazacyclotetradecan-5,12-dione (1013930-96-5) + copper(II) bis(trifluoromethanesulfonate) (34946-82-2) → Cu(1,8-bis(4-[2,2':6',2'']terpyridin-4'-yl-benzyl)-1,4,8,11-tetraazacyclotetradecan-5,12-dione) (1013931-05-9)

Guidance literature:

With K₂CO₃; In methanol; MeOH soln. of Cu(CF3SO3)2 added dropwise to soln. of ligand and K2CO3 inMeOH, refluxed for 12 h; filtered, evapd. under reduced pressure, alumina column chromy. with CH2Cl2:MeOH 96:4; elem. anal.;

DOI:10.1021/ic901832q

Reference yield:

nickel tetrafluoroborate + Cu(1,8-bis(4-[2,2':6',2'']terpyridin-4'-yl-benzyl)-1,4,8,11-tetraazacyclotetradecan-5,12-dione) (1013931-05-9) → CuNi(1,8-bis(4-[2,2':6',2'']terpyridin-4'-yl-benzyl)-1,4,8,11-tetraazacyclotetradecan-5,12-dione)(2+) (1202918-88-4)

Guidance literature:

In methanol; (under inert atm.); Cu-complex mixed with Ni(BF4)2 in MeOH, 1 h, Et2O added; filtered, washed with Et2O, dried under reduced pressure;

DOI:10.1021/ic901832q

Reference yield:

trifluorormethanesulfonic acid (1493-13-6) + Cu(1,8-bis(4-[2,2':6',2'']terpyridin-4'-yl-benzyl)-1,4,8,11-tetraazacyclotetradecan-5,12-dione) (1013931-05-9) → Cu(2+)*N4C10H18O2(CH2C6H4C5H2N(C5H4N)2)2*2SO3CF3(1-)=(Cu(N4C10H18O2(CH2C6H4C5H2N(C5H4N)2)2))(SO3CF3)2

Guidance literature:

In methanol; HSO3CF3 added to MeOH soln. of Cu complex; not isolated; monitored by UV-vis spectra and cyclovoltammetry;

DOI:10.1021/ic701584e

upstream raw materials:

1,8-bis-(4-[2,2';6',2'']terpyridin-4'-yl-benzyl)-1,4,8,11-tetraazacyclotetradecan-5,12-dione

copper(II) bis(trifluoromethanesulfonate)

Downstream raw materials:

CuNi(1,8-bis(4-[2,2':6',2'']terpyridin-4'-yl-benzyl)-1,4,8,11-tetraazacyclotetradecan-5,12-dione)⁽²⁺⁾

CuFe(1,8-bis(4-[2,2':6',2'']terpyridin-4'-yl-benzyl)-1,4,8,11-tetraazacyclotetradecan-5,12-dione)⁽²⁺⁾