potassium 4-fluorophenyltrihydroxyboronate

Base Information

• Chemical Name: potassium 4-fluorophenyltrihydroxyboronate
• CAS No.: 1268613-24-6
• Molecular Formula: C₆H₇BFO₃*K
• Molecular Weight: 196.027
• Mol file: 1268613-24-6.mol

Synonyms:

Chemical Property of potassium 4-fluorophenyltrihydroxyboronate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of potassium 4-fluorophenyltrihydroxyboronate

There total 3 articles about potassium 4-fluorophenyltrihydroxyboronate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

tris(4-fluorophenyl)boroxine (448-59-9) → potassium 4-fluorophenyltrihydroxyboronate (1268613-24-6)

Guidance literature:

With water; potassium hydroxide; In tetrahydrofuran; for 0.333333h; Sonication; Inert atmosphere;

DOI:10.1021/ja1108326

Reference yield:

4-fluoroboronic acid (1765-93-1) → potassium 4-fluorophenyltrihydroxyboronate (1268613-24-6)

Guidance literature:

With water; potassium carbonate; In tetrahydrofuran; at 20 ℃; Inert atmosphere;

DOI:10.1021/ja1108326

Reference yield:

4-fluoroboronic acid (1765-93-1) + water (7732-18-5) + potassium carbonate (584-08-7) → potassium 4-fluorophenyltrihydroxyboronate (1268613-24-6)

Guidance literature:

In water; acetone; byproducts: KHCO3; treatment of boronic acid with K2CO3 in water/acetone (1:1) at 20°C; different concns. of K2CO3 were used; NMR monitoring;

DOI:10.1021/ja1108326

upstream raw materials:

4-fluoroboronic acid

water

potassium carbonate

tris(4-fluorophenyl)boroxine